Product ID:PYROIL NON CHLORINATED BRAKE CLNR CONC
MSDS Date:06/05/2000
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CKYKK

THE VALVOLINE COMPANY

3499 DABNEY DRIVE
LEXINGTON, KY 40512
US

Emergency Phone: 800-274-5263

Info Phone: 859-357-7206

Cage: 72527

VALVOLINE OIL CO

14000 LEXINGTON, KY 40512 US

Telephone: 606-357-7206 / 800-274-5263

Cage: 72527

TOLUENE

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL 100 PPM

ACGIH TLV: 188 MG/M3;50 PPM(S)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL ALCOHOL

CAS: 67-56-1

RTECS: PC1400000

OSHA PEL 260 MG/M3;200 PPM S

ACGIH TLV: 262 MG/M3;200 PPM S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ALIPHATIC PETROLEUM DISTILLATES

CAS: 64742-89-8

Health Hazards Acute and Chronic:EYES: CAN CAUSE EYE IRRITATION,
BLURRED VISION. SKIN: MAY CAUSE MILD SKIN IRRITATION. PROLONGED OR
REPEATED CONTACT MAY DRY AND CRACK THE SKIN. SWALLOWING: SMALL
AMOUNTS OF THIS MATERIAL DURING NORMAL HANDLING IS NOT LIKELY TO
CAUSE HARMFUL EFFECTS. SWALLOWING LARGE AMOUNTS MAY BE HARMFUL.
THIS MATERIAL CAN GET INTO THE LUNGS DURING SWALLOWING OR VOMITING.
THIS RESULTS IN LUNG INFLAMMATION AND OTH ER LUNG INJURY.
INHALATION: BREATHING OF VAPOR OR MIST IS POSSIBLE.
Explanation of Carcinogenicity:NO DATA.
Effects of Overexposure:STOMACH OR INTESTINAL UPSET (NAUSEA, VOMITING,
DIARRHEA), IRRITATION (NOSE, THROAT, AIRWAYS), CENTRAL NERVOUS
SYSTEM DEPRESSSION (DIZZINESS, DROWSINESS, WEAKNESS, FATIGUE,
NAUSEA, HEADACHE, UNCONSCIOU SNESS), AND DEATH.

First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES, HOLDING
EYELIDS APART; SEEK MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED
CLOTHING AND LAUNDER BEFORE REUSE. WASH EXPOSED SKIN WITH SOAP AND
WATER. IF S YMPTOMS PERSIST, SEEK MEDICAL ATTENTION. SWALLOWING:
SEEK MEDICAL ATTENTION. IF INDIVIDUAL IS DROWSY OR UNCONSCIOUS, DO
NOT GIVE ANYTHING BY MOUTH; PLACE INDIVIDUAL ON LEFT SIDE, HEAD
DOWN. FOLLOW DOC TORS OR POISON CONTROL CENTER ADVICE ON WHETHER
TO INDUCE VOMITING. INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING
GIVE ARTIFICIAL RESPIRATION. IF BREATHING DIFFICULT, GIVE OXYGEN.
GET MEDICAL ATTEN TION.

Flash Point Method:TCC
Flash Point:=-6.5C, 20.F
Lower Limits:1.2
Extinguishing Media:REGULAR FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR A SELF-CONTAINED BREATHING APPARATUS WITH
A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WITH
APPROPRIATE TURN-OUT GEAR AND CHEMICAL RESISTANT PERSONAL
PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:MATERIAL IS HIGHLY VOLATILE AND READILY
GIVES OFF VAPORS WHICH MAY TRAVEL OR BE MOVED BY VENTILATION AND
IGNITED BY PILOT LIGHTS, SPARKS, SMOKING, ELECTRIC MOTORS, OR OTHER
IGNITION SOURCES AT DISTANT LOCATIONS. NEVER USE WELDING OR
CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE PRODUCT CAN
IGNITE EXPLOSIVELY.

Spill Release Procedures:SMALL SPILL: ABSORB ON ABSORBENTS. LARGE
SPILL: ELIMINATE IGNITION SOURCES (FLAMES, PILOT LIGHTS, ELECTRICAL
SPARKS). STOP SPILL. PREVENT FROM SPREADING, ENTERING DRAINS,
SEWERS, STREAMS, OTHER BODIES OF WATER. IF RUNOFF OCCURS, NOTIFY
AUTHORITIES AS REQUIRED. PUMP OR VACUUM TRANSFER SPILLED PRODUCT TO
CLEAN CONTAINERS FOR RECOVERY. ABSORB RESIDUAL PRODUCT. SEND
CONTAMINATED MATERIALS TO DISPOSAL.

Handling and Storage Precautions:STORAGE: NOT APPLICABLE. HANDLING:
CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED.
Other Precautions:SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES
(VAPOR, LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THE
DATA SHEET MUST BE OBSERVED. ALL FIVE GALLON PAILS AND LARGER METAL
CONTAINERS INCLU DING TANK CARS AND TANK TRUCKS SHOULD BE GROUNDED
AND/OR BONDED WHEN MATERIAL IS TRANSFERRED.

Respiratory Protection:IF WORKPLACE EXPOSURE LIMIT EXCEEDED, A
NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE
OF PROPER ENVIRONMENTAL CONTROL. OSHA REGULATIONS PERMITS OTHER
NIOSH/MSHA RESPIRATORS (NEGAT IVE PRESSURE TYPE) UNDER SPECIFIED
CONDITIONS (CONSULT INDUSTRIAL HYGIENIST). ENGINEERING OR
ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:WEAR RESISTANT GLOVES SUCH AS NEOPRENE.
Eye Protection:CHEMICAL SPLASH GOGGLES IN COMPLIANCE WITH OSHA
REGULATIONS ARE ADVISED.
Other Protective Equipment:OSHA REGULATIONS ALSO PERMIT OTHER TYPE
SAFETY GLASSES. CONSULT YOUR SAFETY REPRESENTATIVE.
Work Hygienic Practices:NOTE TO PHYSICIAN: THIS PRODUCT CONTAINS
METHANOL WHICH CAN CAUSE INTOXICATION AND CNS DEPRESSION. METHANOL
IS METABOLIIZED TO FORMIC ACID AND FORMALDEHYDE. THESE CAN CAUSE
(CONTD. BELOW)
Supplemental Safety and Health
METABOLIC ACIDOSIS, VISIUAL DISTURBANCES, BLINDNESS. SINCE METABOLISM
IS REQUIRED FOR THESE SYMPTOMS, ONSET MAY BE DELAYED FROM 6 TO 30
HOURS. ETHANOL COMPETES FOR THE SAME METABOLIC PATHWAY AND HAS B
EEN USED TO PREVENT METHANOL METABOLISM. ETHANOL ADMINISTRATION IS
INDICATED IN SYMPTOMATIC (CONTD. SEE "ECOLOGICAL")

HCC:F2
Boiling Pt:=63.9C, 147.F
B.P. Text:@760 MMHG FOR COMPONEN
Vapor Pres:97.680 MMHG @68F
Vapor Density:>1.00AIR=1
Spec Gravity:.803-.809@60F(6.711 LB/GL
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER.
Appearance and Odor:CLEAR, COLORLESS LIQUID; (ODOR-NO DATA)
Percent Volatiles by Volume:>99.0%

Stability Indicator/Materials to Avoid:YES
CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, OPEN FLAME, AND PROLONGED STORAGE AT
ELEVATED TEMPERATURES.
Hazardous Decomposition Products:MAY FORM CARBON DIOXIDE AND CARBON
MONOXIDE, VARIOUS HYDROCARBONS..
Conditions to Avoid Polymerization:PRODUCT WILL NOT UNDERGO HAZARDOUS
POLYMERIZATION.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE, AND FEDERAL REGULATIONS.

Toxicological Information:TARGET ORGAN EFFECTS: OVEREXPOSURE TO THIS
MATERIAL (OR ITS COMPONENTS) HAS BEEN SUGGESTED AS A CAUSE OF THE
FOLLOWING EFFECTS IN LABORATORY ANIMALS, AND MAY AGGRAVATE
PREEXISTING DISORDERS OF THESE ORGANS IN HUMANS: LIVER
ABNORMALITIES, ANEMIA, SPLEEN DAMAGE, NERVOUS SYSTEM DAMAGE, EYE
DAMAGE, KIDNEY DAMAGE, LUNG DAMAGE, BRAIN DAMAGE, OVEREXPOSURE TO
THIS MATERIAL (OR ITS COMPONENTS) HAS BEEN SU GGESTED AS A CAUSE OF
THE FOLLOWING EFFECTS IN HUMANS, AND MAY AGGRAVATE PREEXISTING
DISORDERS OF THESE ORGANS: LIVER ABNORMALITIES, EYE DAMAGE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:(CONTD. FROM "SUPPLIMENTAL SAFETY AND HEALTH") PATENTS OR AT
BLOOD METHANOL CONCENTRATIONS ABOVE 20 UG/DL. METHANOL IS
EFFECTIVELY REMOVED BY HEMODIALYSIS. THIS MATERIAL IS AN ASPIRATION
HAZARD. POTEN TIAL DANGER FROM ASPIRATION MUST BE WEIGHED AGAINST
POSSIBLE ORAL TOXICITY WHEN DECIDING WHETHER TO INDUCE VOMITING..

Transport Information:DOT INFORMATION, 49 CFR 172.101: DOT DESCRIPTION:
FLAMMABLE LIQUIDS, N.O.S., 3, UN 1993, I I. N.O.S. COMPONENTS:
TOLUENE. PETROLEUM NAPHTHA. CONTAINER/MODE: DRUMS/SURFACE - NO
EXCEPTIONS. RQ(REPORTABL E QUANTITY) - 49 CFR 172.101. COMPONENT:
TOLUENE; QUANTITY = 2066 LBS; METHANOL; QUANTITY = 16,954 LBS.

SARA Title III Information:SARA 302 COMPONENTS - CFR 355 APPENDIX A:
NONE. SECTION 311/312 HAZARD CLASS - 40 CFR 370.2: IMMEDIATE;
DELAYED; FIRE. SARA 313 COMPONENTS - 40 CFR 372.65: SECTION 313
COMPONENTS: TOLUENE, CAS#108-88- 3; METHANOL, CAS#67-56-1.
Federal Regulatory Information:TSCA (TOXIC SUBSTANCES CONTROL ACT)
STATUS: TSCA (UNITED STATES) THE INTENTIONAL INGREDIENTS OF THIS
PRODUCT ARE LISTED. CERCLA RQ - 40 CFR 302.4: TOLUENE: RQ = 1000
LBS; METHYL ALCOHOL: RQ = 5000 LBS .
State Regulatory Information:CALIFORNIA PROPOSITION 65: THE FOLLING
STATEMENT IS MADE IN ORDER TO COMPLY WITH THE CALIFORNIA SAFE
DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986: THIS PRODUCT
CONTAINS THE FOLLOWING SUBSTANCE KNO WN TO THE STATE OF CALIFORNIA
TO CAUSE REPRODUCTIVE HARM. COMPONENT: TOLUENE. NEW JERSEY RTX
LABEL INFORMATION: TOLUENE, CAS#108-88-3; METHYL ALCOHOL, CAS#
67-56-1; NAPHTHA - SOLVENT, CAS#64742-89- 8. PENNSYLVANIA RTX
LABEL INFORMATION: BENZENE, METHYL-, CAS#108-88-3; METHANOL, CAS#
67-56-1.