Product ID:69110, QUAKER STATE AUTOGUARD ANTIFREEZE/COOLANT
MSDS Date:07/27/1995
FSC:6850
NIIN:00-181-7940
Status Code:A
MSDS Number: CKZPW

QUAKER STATE CORPORATION

OIL CITY, PA 16301

Emergency Phone: 814-676-7676

Info Phone: (814) 676-7676

Preparer: DENNIS CRALLEY

Cage: DO899

QUAKER STATE OIL REFINING CORPORATION

989 OIL CITY, PA 16301 US

Telephone: 814-676-7676

Cage: DO899

ETHYLENE GLYCOL

CAS: 107-21-1

RTECS: KW2975000

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

SODIUM BORATE PENTAHYDRATE

CAS: 11130-12-4

SODIUM NITRITE

CAS: 7632-00-0

RTECS: RA1225000

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

SODIUM METASILICATE

CAS: 6834-92-0

RTECS: VV9275000

SODIUM HYDROXIDE

CAS: 1310-73-2

RTECS: WB4900000

OSHA PEL 2 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SODIUM NITRATE

CAS: 7631-99-4

RTECS: WC5600000

LD50 LC50 Mixture:NONE GIVEN FOR MIXTURE AS A WHOLE
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: THIS PRODUCT MAY CAUSE SEVERE
EYE IRRITATION. THIS PRODUCT CAN CAUSE PROLONGED VISION
IMPAIRMENT. SKIN: THIS PRODUCT MAY BE HARMFUL IF IT IS ABSORBED
THROUGH THE SKIN. INGESTION: THIS PRODUC T MAY BE FATAL IF IT IS
SWALLOWED. THIS PRODUCT MAY CAUSE NERVOUS SYSTEM DAMAGE IF
SWALLOWED. SWALLOWING LARGE VOLUMES OF ETHYLENE GLYCOL CAN LEAD TO
KIDNEY DAMAGE. INHALATION: EXPOSURE TO HIGH CONC ENTRATIONS OF
VAPOR MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. EXPOSURE TO
VAPOR MAY CAUSE DAMAGE TO KIDNEYS, LIVER, LUNGS AND BLOOD.
Explanation of Carcinogenicity:NONE OF THIS PRODUCT'S COMPONENTS ARE
LISTED BY ACGIH, IARC, NIOSH, NTP OR OSHA.
Effects of Overexposure:EYES: TEARS, SWELLING, REDNESS. INGESTION: MAY
CAUSE DIZZINESS, INCOORDINATION, HEADACHE, NAUSEA, VOMITING.
CARDIAC FAILURE & PULMONARY EDEMA MAY DEVELOP AFTER INGESTION OF
THIS MATERIAL. CASES OF UNC ONSCIOUSNESS & NYSTAGMUS. INHALATION:
EXCESSIVE INHALATION OF THIS PRODUCT MAY CAUSE HEADACHE, DIZZINESS,
BLURRED VISION, NAUSEA AND VOMITING. EXPOSURE TO HIGH
CONCENTRATIONS OF VAPOR MAY CAUSE CENTR AL NERVOUS SYSTEM
DEPRESSION. EXPOSURE TO VAPORS MAY CAUSE DAMAGE TO THE KIDNEYS,
LIVER, LUNGS AND BLOOD.
Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY MANUFACTURER

First Aid:EYE: IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH
PLENTY OF WATER AND SEEK MEDICAL ADVICE. IF EYES BECOME INFLAMMED,
SEEK MEDICAL ADVICE. SKIN: FOR SKIN CONTACT, FLUSH WITH LARGE
AMOUNTS OF WA TER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
INGESTION: IF THE MATERIAL IS SWALLOWED, GET IMMEDIATE MEDICAL
ATTENTION OR ADVICE -- DO NOT INDUCE VOMITING. INHALATION: IF
GAS/FUME/VAPOR/DUST /MIST FROM THE MATERIAL IS INHALED, REMOVE THE
AFFECTED PERSON IMMEDIATELY TO FRESH AIR. IF THE AFFECTED PERSON
IS NOT BREATHING, APPLY ARTIFICAL RESPIRATION. NOTES TO PHYSICIAN:
ETHANOL IS AN ANTID OE FOR FOR ETHYLENE GLYCOL INGESTION.

Flash Point Method:TCC
Flash Point:=115.6C, 240.F
APPROX.
Autoignition Temp:Autoignition Temp Text:N/AV
Lower Limits:3.2
Upper Limits:NONE
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE, WATER FOG. USE
WATER TO COOL FIRE-EXPOSED CONTAINERS AND TO PROTECT PERSONNEL. A
SOLID STREAM OF WATER MAY SCATTER MOLTEN PRODUCT
Fire Fighting Procedures:WEAR FULL SET OF PROTECTIVE EQUIPMENT,
INCLUDING CHEMICAL GOGGLES AND GLOVES
Unusual Fire/Explosion Hazard:SHUT OFF THE SOURCE OF FUEL, IF POSSIBLE.
THIS PRODUCT MAY REACT EXPLOSIVELY WHEN MIXED WITH OXIDIZING
AGENTS. A SUDDEN RELEASE OF HOT ORGANIC VAPORS/MISTS FROM THE
PROCESS EQUIPMENT AT ELEVATED TEMPE RATURES AND PRESSURES MAY
RESULT IN IGNITIONS WITHOUT THE PRESENCE OF AN OBVIOUS IGNITION
SOURCE.

Spill Release Procedures:STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT
RISK. DIKE THE SPILLED MATERIAL, WHERE THIS IS POSSIBLE. ABSORB
WITH INERT ABSORBENT SUCH AS DRY CLAY, SAND OR DIATOMACEOUS EARTH,
COMMERCIAL SORBENTS, O R RECOVER USING PUMPS. SCOOP UP USED
ABSORBENT INTO DRUMS. WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
CLOTHING DURING CLEAN-UP. THOROUGHLY WASH THE AREA AFTER A SPILL
OR LEAK CLEAN-UP. ISOLATE AREA
Neutralizing Agent:NO DATA PROVIDED BY MANUFACTURER

Handling and Storage Precautions:HANDLING: DO NOT GET THIS MATERIAL IN
YOUR EYES, ON YOUR SKIN, OR ON YOUR CLOTHING. KEEP THIS PRODUCT
FROM HEAT, SPARKS, OR OPEN FLAME. USE THIS PRODUCT WITH ADEQUATE
VENTILATION. DO NOT REUSE THE EMPTY CONTAINER. WASH THOROUGHLY
AFTER HANDLING. STORAGE: KEEP THIS MATERIAL AWAY FROM FOOD,
Other Precautions:PROTECT FROM SKIN AND EYE CONTACT. KEEP THIS PRODUCT
AWAY FROM CHILDREN AND PETS.

Respiratory Protection:USE AN ORGANIC VAPOR RESPIRATOR FOR
CONCENTRATIONS EXCEEDING THE OCCUPATIONAL EXPOSURE LIMIT. USE
SUPPLIED-AIR RESPIRATORY EQUIPMENT AS REQUIRED
Ventilation:LOCAL EXHAUST IS SUGGESTED FOR USE, WHERE POSSIBLE, IN
ENCLOSED OR CONFINED SPACES
Protective Gloves:POLYVINYL CHLORIDE GLOVES IS RECOMMENDED
Eye Protection:SAFETY GLASSES WITH SIDE SHIELDS
Other Protective Equipment:PROTECTIVE COVERALLS AND LONG SLEEVES IS
RECOMMENDED. EYEWASH FOUNTAINS AND EMERGENCY SHOWERS ARE REQUIRED
Work Hygienic Practices:USE GOOD INDUSTRIAL HYGIENE PRACTICES.
Supplemental Safety and Health
NSN CANCELLED: 00092. PER SAMMS-CTDF USE NSN: 6850-01-441-3223.

HCC:V5
Spec Gravity:1.12 TO 1.13
pH:10.8
Appearance and Odor:LIQUID, FLUORESCENT GREEN, ODOR: NOT AVAILABLE

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS (PEROXIDES, CHLORINE, STRONG ACIDS). AVOID
MIXING WITH STRONG ACID AND BASES AT ELEVATED TEMPERATURES TO AVOID
EXPOLOSIVE DECOMPOSITION.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT AND ALL SOURCES OF
IGNITION.
Hazardous Decomposition Products:SMOKE, CARBON MONOXIDE AND CARBON
DIOXIDE
Conditions to Avoid Polymerization:WILL NOT OCCUR

Waste Disposal Methods:PRODUCT AS SHIPPED DOES NOT MEET THE DEFINITION
OR CHARACTERISTICS OF A HAZARDOUS WASTE. DO NOT ALLOW THIS MATERIAL
TO DRAIN INTO SEWERS/WATER SUPPLIES. ALL WASTES MUST BE HANDLED IN
ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.

Toxicological Information:INGESTION OF ETHYLENE GLYCOL CAN CAUSE KIDNEY
AND LIVER DAMAGE, METABOLIC ACIDOSIS, PULMONARY EDEMA. CRYSTALS OF
CALCIUM OXALATE WILL FORM IN KIDNEY AND IN THE BLOOD VESSELS OF THE
BRAIN. LD50/LC50: E THYLENE GLYCOL (107-21-1): ORAL RAT: LD50 =
4700 MG/KG; SKIN RABBIT: LD50 = 9530 MG/KG. SODIUM NITRATE
(7632-00-0): ORAL RAT: LD50 = 85 MG/KG. SODIUM METASILICATE
(6834-92-0): ORAL, RAT: LD50 = 1153 M G/KG. SODIUM NITRATE
(7631-99-4): ORAL, RAT: LD50 = 3236 MG/KG. EPIDEMIOLOGY: THE
MAJORITY OF REPORTED ETHYLENE GLYCOL FATALITIES ARE DUE TO KIDNEY
FAILURE. SEE OTHER INFORMATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICITY: KEEP PRODUCT OUT OF SEWERS. ENVIRONMENTAL FATE:
IN AN AQUATIC ENVIRONMENT, ETHYLENE GLYCOL WILL BIODEGRADE READILY
AND HAVE A HALF-LIFE OF SEVERAL DAYS. IN THE ATMOSPHERE ETHYLENE
GLYCOL WILL REACT WITH HYDROXYL RADICALS; IT WILL HAVE A HALF-LIFE
OF TWO DAYS. THE FATE OF ETHYLENE GLYCOL IN SOIL IS AS OF YET,
UNKNOWN.

Transport Information:SHIPPING NAME: NOT REGULATED. HAZARD CLASS: NOT
REGULATED. UN/NA #: NOT REGULATED. PACKING GROUP: NOT REGULATED.
LABEL(S) REQUIRED: NO LABELS REQUIRED. ADDITIONAL SHIPPING
INFORMATION: NONE. INTERNATI ONAL TRANSPORTATION REGULATIONS: NOT
REGULATED AS DANGEROUS GOODS.

SARA Title III Information:ETHYLENE GLYCOL (107-21-1, >95%): SARA 313:
FORM R REPORTING REQUIRED FOR 1.0% DE MINIMUS CONCENTRATION.
CERCLA: FINAL RQ = 1 POUND (0.454 KG). SODIUM NITRATE (7632-00-0,
<1%): SARA 313: FORM R REPORT ING REQUIRED. CERCLA: FINAL RQ = 100
POUNDS (45.4 KG). SODIUM HYDROXIDE (1310-73-2, <0.5%): CERCLA:
FINAL RQ = 1000 POUNDS (454 KG).
Federal Regulatory Information:NO DATA PROVIDED BY MANUFACTURER.
State Regulatory Information:THE FOLLOWING COMPONENTS APPEAR ON ONE OR
MORE OF THE FOLLOWING STATE HAZARDOUS SUBSTANCE LISTS: ETHYLENE
GLYCOL, 107-21-1: CA, FL, MA, MN, NJ, PA; SODIUM NITRITE,
7632-00-0: CA, MA, NJ, PA; SODIUM HY DROXIDE, 1310-73-2: CA, FL,
MA, MN, NJ, PA; SODIUM NITRATE, 7631-99-4: FL, MA, NJ, PA.