Product ID:212334, HYJET IV-A PLUS
MSDS Date:06/01/1999
FSC:9150
NIIN:01-096-6497
Status Code:A
MSDS Number: CKZXM

EXXON COMPANY USA

HOUSTON, TX 77252-2180
US

Emergency Phone: 281-834-3296 (BAYTOWN)

Info Phone: 713-656-5949; 800-298-4007

Preparer: NOT PROVIDED.

Cage: DO849

EXXON MOBIL LUBRICANTS AND PETROLEUM SPECIALTIES CO.

FAIRFAX, VA 22037 US

Telephone: 703-846-4240

Cage: 0TS34

TRIBUTYL PHOSPHATE

CAS: 126-73-8

RTECS: TC7700000

OSHA PEL 5 MG/M3

ACGIH TLV: 2.2 MG/M3;0.2 PPM

AROMATIC PHOSPHATES

OSHA PEL NOT PROVIDED.

ACGIH TLV: NOT PROVIDED.

POLYMER ADDITIVES

OSHA PEL NOT PROVIDED.

ACGIH TLV: NOT PROVIDED.

ALIPHATIC EPOXIDES

OSHA PEL NOT PROVIDED.

ACGIH TLV: NOT PROVIDED.

LD50 LC50 Mixture:LD50 (ORAL, RAT) > 5G/KG OF BODY WEIGHT
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:PROLONGED OR REPEATED SKIN CONTACT MAY
CAUSE SKIN IRRITATION. REPEATED AND PROLONGED OVEREXPOSURE TO OIL
MISTS MAY RESULT IN DROPLET DEPOSITION, OIL GRANULOMA FORMATION,
INFLAMMATION AND INCREASED INC IDENCE OF INFECTION. PROLONGED OR
REPEATED CONTACT WITH THIS PRODUCT TENDS TO REMOVE SKIN OILS,
POSSIBLY LEADING TO IRRITATION AND DERMATITIS. PRODUCT CONTACTING
THE EYES WILL CAUSE EYE IRRITATION. PR ODUCT HAS A LOW ORDER OF
ACUTE ORAL AND DERMAL TOXICITY, BUT MINUTE AMOUNTS ASPIRATED INTO
THE LUNGS DURING INGESTION OR VOMITING MAY CAUSE MILD TO SEVERE
PULMONARY INJURY AND POSSIBLY DEATH.
Explanation of Carcinogenicity:IN ACCORDANCE WITH THE CURRENT OSHA
COMMUNICATION STANDARD CRITERIA, THIS PRODUCT DOES NOT REQUIRE A
CANCER HAZARD WARNING. THIS PRODUCT CONTAINS SYNTHETICALLY DERIVED
MATERIALS, AND AS SUCH IS NOT CH ARACTERIZED BY CURRENT IARC
CLASSIFICATION CRITERIA FOR OILS.
Effects of Overexposure:PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE
SKIN IRRITATION. PRODUCT MAY DECOMPOSE AT ELEVATED TEMPERATURES OR
UNDER FIRE CONDITIONS AND GIVE OFF IRRITATING, NOXIOUS AND TOXIC
VAPORS/FUMES. SYMPTOMS FROM ACUTE EXPOSURE IN CONFINED SPACES MAY
INCLUDE HEADACHE, NAUSEA, EYE, NOSE AND THROAT IRRITATION. WITH
PROLONGED EXPOSURE, SERIOUS HEALTH ONSEQUENCES SUCH AS LUNG DAMAGE
AND DEATH MAY OCCUR IF EX POSURES ARE ALLOWED TO CONTINUE WITHOUT
PROPER RESPIRATORY PROTECTION.
Medical Cond Aggravated by Exposure:NONE RECOGNIZED.

First Aid:EYE CONTACT: IF SPLASHED INTO THE EYES, FLUSH WITH CLEAR
WATER FOR 15 MINUTES OR UNTIL IRRITATION SUBSIDES. IF IRRITATION
PERSISTS, CALL PHYSICIAN. SKIN: IN CASE OF CONTACT, WASH WITH SOAP
AND WATER. IF INJECTED INTO/UNDER SKIN, REGARDLESS OF THE
APPEARANCE OR ITS SIZE, CONTACT PHYSICIAN IMMEDIATELY. INHALATION:
VAPOR PRESSURE IS LOW AND INHALATION NORMALLY IS NOT A PROBLEM. IF
OVERCOME BY VAPOR F ROM HOT PRODUCT, IMMEDIATELY REMOVE FROM
EXPOSURE AND CALL A PHYSICIAN. IF BREATHING IS IRREGULAR/HAS
STOPPED, START RESUSCITATION, ADMINISTER OXYGEN IF AVAILABLE.
INGESTION: IF INGESTED, DO NOT INDUC E VOMITING; CALL PHYSICIAN
IMMEDIATELY.

Flash Point Method:COC
Flash Point:=177.8C, 352.F
MINIMUM
Autoignition Temp:=407.8C, 766.F
Lower Limits:NOT AVAILABL
Upper Limits:NOT AVAILABL
Extinguishing Media:FOAM, WATER SPRAY (FOG), DRY CHEMICAL, CARBON
DIOXIDE AND VAPORIZING LIQUID TYPE EXTINGUISHING AGENTS MAY ALL BE
SUITABLE FOR EXTINGUISHING FIRES INVOLVING THIS TYPE OF PRODUCT.
Fire Fighting Procedures:USE WATER TO KEEP FIRE EXPOSED CONTAINERS
COOL. IF A LEAK/SPILL HAS NOT IGNITED, USE WATER SPRAY TO DISPERSE
THE VAPORS AND TO PROVIDE PROTECTION FOR PERSONS ATTEMPTING TO STOP
A LEAK. WATER SPRAY MAY BE USED TO FLUSH SPILLS AWAY. USE
SUPPLIED-AIR BREATHING EQUIPMENT FOR ENCLOSED/CONFINED SPACES OR AS
OTHERWISE NEEDED.
Unusual Fire/Explosion Hazard:NOT PROVIDED.

Spill Release Procedures:RECOVER FREE PRODUCT. ADD SAND, EARTH OR OTHER
SUITABLE ABSORBENT TO SPILL AREA. MINIMIZE BREATHING VAPORS.
MINIMIZE SKIN CONTACT. OPEN ALL WINDOWS AND DOORS. KEEP PRODUCT OUT
OF SEWERS AND WATERCOURS ES BY DIKING OR IMPOUNDING. ADVISE
AUTHORITIES IF PRODUCT HAS ENTERED OR MAY ENTER SEWERS,
WATERCOURSES, OR EXTENSIVE LAND AREAS. ASSURE CONFORMITY WITH
APPLICABLE GOVERNMENTAL REGULATIONS.
Neutralizing Agent:NOT RELEVANT.

Handling and Storage Precautions:USE PRODUCT WITH CAUTION AROUND HEAT,
SPARKS, PILOT LIGHTS, STATIC ELECTRICITY, AND OPEN
FLAME.
Other Precautions:"EMPTY" CONTAINERS RETAIN RESIDUE (LIQUID AND/OR
VAPOR) AND CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD,
BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO
HEAT, FLAME, SPARKS, S TATIC ELECTRICITY, OR OTHER SOURCES OF
IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.

Respiratory Protection:USE SUPPLIED-AIR RESPIRATORY PROTECTION IN
CONFINED OR ENCLOSED SPACES, IF NEEDED.
Ventilation:USE LOCAL EXHAUST, IF NECESSARY. PROVIDE VENTILATION
SUFFICIENT TO PREVENT EXCEEDING RECOMMENDED EXPOSURE LIMIT OR
BUILDUP OF EXPLOSIVE CONCENTRATIONS OF VAPOR
Protective Gloves:USE CHEMICAL RESISTANT GLOVES TO AVOID PROLONGED OR
REPEATED SKIN CONTACT.
Eye Protection:USE SPLASH GOGGLES OR FACE SHIELD WHEN EYE CONTACT MAY
OCCUR.
Other Protective Equipment:USE CHEMICAL-RESISTANT APRON OR OTHER
IMPERVIOUS CLOTHING, IF NEEDED, TO AVOID CONTAMINATING REGULAR
CLOTHING, WHICH COULD RESULT IN PROLONGED OR REPEATED SKIN
CONTACT.
Work Hygienic Practices:TO PREVENT FIRE OR EXPLOSION RISK FROM STATIC
ACCUMULATION AND DISCHARGE, EFFECTVELY BOND AND/OR GROUND PRODUCT
TRANSFER SYSTEM IN ACCORDANCE WITH THE NATIONAL FIRE PROTECTION
ASSOCIATION PUBLICATIONS.
Supplemental Safety and Health
MINIMIZE BREATHING VAPOR, MIST OR FUMES. AVOID PROLONGED OR REPEATED
CONTACT WITH SKIN. REMOVE CONTAMINATED CLOTHING AND LAUNDER OR
DRY-CLEAN BEFORE REUSE. ABBREVIATION: N/A = NOT APPLICABLE. N/AV =
N OT AVAILABLE. N/K = UNKNOWN. N/P = NOT PROVIDED. N/R = NOT
RELEVANT. N/D = NOT DETERMINED. N/E = NOT ESTABLISHED.

HCC:V6
NRC/State Lic Num:NOT RELEVANT.
Boiling Pt:=287.8C, 550.F
B.P. Text:APPROXIMATELY
Melt/Freeze Pt:=-56.5C, -70.F
M.P/F.P Text:POUR POINT
Decomp Temp:Decomp Text:NOT PROVIDED.
Vapor Pres:0.5 @ 200F
Vapor Density:N/AV
Spec Gravity:0.995
pH:NEUTRAL
Viscosity:10.33 CST @ 100F
Evaporation Rate & Reference:NO DATA
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR PURPLE LIQUID, SWEET ODOR
Percent Volatiles by Volume:NEGLIGIBLE
Corrosion Rate:NOT PROVIDED.

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDANTS SUCH AS LIQUID CHLORINE,
CONCENTRATED OXYGEN, SODIUM HYPOCHLORITE, CALCIUM HYPOCHLORITE,
NITRATES, PEROXIDES, ETC., AS THIS PRESENT A SERIOUS EXPLOSION
HAZARD.
Stability Condition to Avoid:WILL NOT REACT WITH WATER.
Hazardous Decomposition Products:FUMES, SMOKE, CARBON MONOXIDE, SULFUR
OXIDES, NITROGEN OXIDES, PHOSPHORUS OXIDES, ALDEHYDES AND OTHER
DECOMPOSITION PRODUCTS, IN THE CASE OF INCOMPLETE COMBUSTION.

Waste Disposal Methods:OPTIONS FOR DISPOSAL OF THIS PRODUCT MAY DEPEND
ON THE CONDITIONS UNDER WHICH IT WAS USED. TO DETERMINE THE
PROPER METHOD OF DISPOSAL, REFER TO RCRA (40 CFR 261), AS
WELL AS FEDERAL EPA AND STATE AND LOCAL REGULATIONS.

Toxicological Information:THIS PRODUCT CONTAINS A TRIARYLPHOSPHATE
WHICH WHEN GIVEN IN LARGE ORAL DOSES (4 G/KG) TO HENS CAUSED
DELAYED NERVE DAMAGE THAT RESULTED IN LOSS OF
COORDINATION AND DIFFICULTY IN WALKI NG; THESE EFFECTS WERE NOT
OBSERVED IN HENS GIVEN 2 G/KG. THIS PRODUCT IS JUDGED TO HAVE AN
ACUTE ORAL LD50 (RAT) GREATER THAN 5 G/KG OF BODY WEIGHT, AND AN
ACUTE DERMAL LD50 (RABBIT) GREATER TH AN 3.16 G/KG OF BODY
WEIGHT.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:DO NOT DISCHARGE THIS PRODUCT INTO PUBLIC WATERS OR
WATERWAYS UNLESS AUTHORIZED BY A NATIONAL POLLUTION
DISCHARGE ELIMINATION SYSTEM (NPDES) PERMIT ISSUED BY THE
ENVIRONMENTAL PROTECTI ON AGENCY (EPA). ENVIRONMENTAL AND
ECOLOGICAL DATA MAY BE AVAILABLE FOR THIS PRODUCT. WRITE OR
CALL EXXON TO OBTAIN FURTHER INFORMATION. REFER TO SECTION 6 AND
SECTION 15 FOR ACCIDENTA L RELEASE INFORMATION AND REGULATORY
REPORTING INFORMATION.

Transport Information:U.S. DOT HAZARDOUS MATERIALS SHIPPING DESCRIPTION
TRANSPORTED BY HIGHWAY, RAIL OR AIR (49 CFR 171-180): BULK
PACKAGINGS (CAPACITY GREATER THAN 119 U.S. GALLONS:)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (TRIARYL
PHOSPHATES, ISOPROPYLATED), 9, UN 3082, III, MARINE POLLUTANT.
NON-BULK PACKAGINGS (CAPACITY LESS THAN OR EQUAL TO 119 U.S.
GALLONS): NOT REGULATED (49 CFR 171-180, IATA DGR 7.1.5.2)
TRANSPORTED BY MARINE VESSEL: BULK AND NON-BULK PACKAGINGS (IMDG
7.2.1): ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(TRIARYL PHOSPHATES, ISOPROPYLATED), 9, UN 3082, III, MARINE POL
LUTANT

SARA Title III Information:THRESHOLD PLANNING QUANTITY (TPQ), EPA
REGULATION 40 CFR 355 (SARA SECTIONS 301-304)
NO TPQ
FOR PRODUCT OR ANY CONSTITUE NT GREATER THAN 1% OR 0.1%
(CARCINOGEN). HAZARDOUS CHEMICAL REPORTING, EPA REGULATION 40 CFR
370 (SARA SECTIONS 311-312) EPA HAZARD CLASSIFICATION CODES:
ACUTE, CHRONIC
Federal Regulatory Information:ALL COMPONENTS OF THIS PRODUCT ARE
LISTED ON THE U.S. TSCA INVENTORY. TOXIC SUBSTANCES CONTROL ACT
(TSCA) THIS PRODUCT CONTAINS THE FOLLOWING TSCA 12B
REPORTABLE CHEMICAL SUBSTANCE(S): TRIBUTYL PHOSPHATE CAS #
126-73-8 TOXIC CHEMICAL RELEASE REPORTING, EPA REGULATION 40 CFR
372 (SARA SECTION 313) NO TOXIC CHEMICAL IS PRESENT GREATER
THAN 1% OR 0.1% (CARCINOGEN).