Product ID:ED85 FUEL ETHANOL
MSDS Date:07/05/1995
FSC:6850
NIIN:01-478-7591
Status Code:A
MSDS Number: CLCVN

ARCHER DANIELS MIDLAND CO

4666 E FARIES PKWY
DECATUR, IL 62526-5666
US

Emergency Phone: 217-362-3980

Info Phone: 217-424-5200/7418

Cage: 84168

SDB CONSULTANTS LTD

GRETNA, LA 70056 US

Telephone: 504-366-9105

Cage: 0PGK2

ETHYL ALCOHOL (200 PROOF)

CAS: 64-17-5

RTECS: KQ6300000

OSHA PEL 1900 MG/M3;1000 PPM

ACGIH TLV: 1880 MG/M3;1000 PPM

NATURAL GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

ACGIH TLV: 890 MG/M3;300 PPM

BENZENE

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <1100%PPM

OSHA PEL 1 PPM

ACGIH TLV: 10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

LD50 LC50 Mixture:.05 TO 5 G/KG
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:YES
Health Hazards Acute and Chronic:MAY CAUSE MUCOUS MEMBRANE IRRITATION:
UNCONSCIOUSNESS: COMA; RESPIRATORY FAILURE AND DEATH. MAY CAUSE
SKIN IRRITATION AS A RESULT OF DEFATTING. GASTROINTESTINAL
IRRITATION, VOMITTING, CNS DEPRESSION, COMA.
Effects of Overexposure:MAY CAUSE DIZZINESS, LOSS OF BALANCE AND
COORDINATION. MAY CAUSE MUCOUS MEMBRANE IRRITATION:
UNCONSCIOUSNESS: COMA; RESPIRATORY FAILURE AND DEATH. MAY CAUSE
SKIN IRRITATION AS A RESULT OF DEFATTING. GASTROINTESTINAL
IRRITATION, VOMITTING, CNS DEPRESSION, COMA.
Medical Cond Aggravated by Exposure:NOT DETERMINED

First Aid:IF SWALLOWED, DO NOT INDUCE VOMITING. IF INHALED. REMOVE
PERSON TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS
STOPPED. CALL A PHYSICIAN. IF SPLASHED IN EYES OR ON SKIN, FLUSH
IMMEDIATELY WITH COPIOUS AMOUNTS OF WATER.

Flash Point Method:TCC
Flash Point:-20F TO -4F
Lower Limits:1.4
Upper Limits:19.0
Extinguishing Media:CARBON DIOXIDE DRY CHEMICAL, WATER FOR SMALL FIRES.
PLAR SOLVENT FOAM FOR LARGE FIRES.
Fire Fighting Procedures:USE NECESSARY PROTECTIVE EQUIPMENT AND
BREATHNG APPARATUS AS WOULD NORMALLY BE USED WHEN FIGHTING FIRES
WHERE THERE MAY BE DANGER OF BREATHING HAZARDOUS PRODUCTS OF
COMBUSTION.
Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID.

Spill Release Procedures:ELEMINATE ALL SOURCES OF IGNITION. SMALL
SPILLS SHOULD BE FLUSHED WITH LARGE QUANTITIES OF WATER. LARGE
SPILLS SHOULD BE COLLECTED FOR WASTE DISPOSAL.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, & OPEN
FLAMES. KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION.
Other Precautions:USE EXPLOSION PROOF ELECTRICAL EQUIPMENT AND
NON-SPARKING TOOLS. GROUND ELECTRICAL EQUIPMENT.

Respiratory Protection:AIR SUPPLIED MASK FOR HIGH CONCENTRATIONS.
Ventilation:LOCAL: PREFERRED. MECHANICAL(GENERAL): ACCEPTABLE SPECIAL:
NONE. OTHER: NONE.
Protective Gloves:RUBBER.
Eye Protection:GOGGLES.
Other Protective Equipment:EYE BATH AND SAFETY SHOWER.
Work Hygienic Practices:NA
Supplemental Safety and Health
IDENTITY: FUEL ETHANOL ED85.

HCC:F2
Boiling Pt:=76.7C, 170.F
Melt/Freeze Pt:M.P/F.P Text:NA
Vapor Pres:(MMHG)@100F 340-560
Vapor Density:2.0-4.0
Spec Gravity:(H2O=1)0.76-0.78
Evaporation Rate & Reference:(BUTYL ACETATE=1)NOT ESTI
Solubility in Water:60-70 GM/100ML
Appearance and Odor:CLEAR, COLORLESS VOLATILE LIQUID WITH AN ETHEREAL
ODOR

Stability Indicator/Materials to Avoid:NO
MAY REACT VIGOROUSLY WITH OXIDIZING MATERIALS.
Stability Condition to Avoid:NONE IN NORMAL USE.
Hazardous Decomposition Products:COMBUSTION MAY PRODUCE COX, NOX AND
REACTIVE HYDROCARBONS.
Conditions to Avoid Polymerization:WILL NOT OCCUR

Waste Disposal Methods:DO NOT ALLOW TO ENTER SEWERS WHERE VAPORS MAY
BECOME IGNITED. INCINERATE IN A FURNACE WHERE PERMITTED UNDER
APPROPRIATE FEDERAL, STATE AND LOCAL REGULATIONS OR DISPOSE OF IN A
SITE STIPULATED FOR HAZA RDOUS MATERIALS.

Toxicological Information:NO DATA PROVIDED BY MANUFACTURER

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO DATA PROVIDED BY MANUFACTURER

Transport Information:NO DATA PROVIDED BY MANUFACTURER

SARA Title III Information:NO DATA PROVIDED BY MANUFACTURER
Federal Regulatory Information:NO DATA PROVIDED BY MANUFACTURER
State Regulatory Information:BENZENE, CAS# 71-43-2, <1100 PPM: A
CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CAANCER.