Product ID:FYRQUEL 220 MLT
MSDS Date:01/01/1992
FSC:9150
NIIN:01-113-2045
Status Code:A
MSDS Number: CLDNP

AKZO NOBEL CHEMICALS INC

300 S. RIVERSIDE PLAZA
CHICAGO, IL 60606-6613
US

Emergency Phone: 312-906-7054 800-424-9300(CHEMTREC)

Info Phone: 800-828-792

Cage: 97854

SDB CONSULTANTS LTD

GRETNA, LA 70056 US

Telephone: 504-366-9105

Cage: 0PGK2

PHOSPHORIC ACID (1,1,-DIMETHYLETHYL- PHENYL DIPHENYL ESTER)

CAS: 56803-37-3

PHOSPHORIC ACID BIS{(1.1-DIMETHYLETHYL)-PHENYL}PHENYL

CAS: 65652-41-7

TRIPHENYL PHOSPHATE

CAS: 115-86-6

RTECS: TC8400000

1)

CAS: 78-33-1

BUTYLATED TRIPHENYL PHOSPHATE

LD50 LC50 Mixture:ORAL LD50 (RAT) IS >5000MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Health Hazards Acute and Chronic:THE PRINCIPAL ROUTES OF EXPOSURE ARE
SKIN CONTACT & INHALATION. SKIN & EYE CONTACT MAY RESULT IN
IRRITATION. INHALATION OF VAPORS MAY CAUSE RESPIRATORY IRRITATION.
Explanation of Carcinogenicity:THE PRODUCT WAS EXAMINED IN AN VITRO
MALIGNANT TRANSFORMATION TEST UTILIZING BALB/3T3 CELLS. THE PRODUCT
DID NOT INDUCE MORPHOLOGIC TRANSFORMATIONS & THUS DID NOT EXHIBIT
CARCINOGENIC POTENTIAL IN THI S TEST.
Effects of Overexposure:TRIPHENYL PHOSPHATE HAS BEEN REPORTED TO BE A
CHOLINESTERASE INHIBITOR. SYMPTOMS OF CHOLINESTERASE INHIBITION MAY
INCLUDE SALIVATION, SWEATING, HEADACHE, NAUSEA, MUSCLE TWITCHING,
TREMORS, INCOORDINAT ION, BLURRED VISION, TEARS, ABDOMINAL CRAMPS,
DIARRHEA, CHEST DISCOMFORT. SEVERE CHOLINESTERASE INHIBITION MAY
LEAD TO CONVILSIONS, PULMONARY EDEMA, RESPIRATORY FAILURE & DEATH.

First Aid:CONTACT A POISON CENTER, PHYSICIAN OR THE NEAREST HOSPITAL.
INGESTED-IMMEDIATELY GIVE SEVERAL GLASSES WATER BUT DO NOT INDUCE
VOMITING. HAVE PHYSICIAN DETERMINE IF VOMITING INDUCTION OR STOMACH
EVACUA TION IS NEEDED. NOTHING BY MOUTH IF UNCONSCIOUS. SKIN-FLUSH
WITH WATER WHILE REMOVING CONTAMINATED CLOTHES. GET MEDICAL
ATTENTION IF IRRITATION OCCURS. WASH CLOTHES BEFORE REUSE.
EYES-IMMEDIATELY FL USH WITH LOTS OF RUNNING WATER FOR AT LEAST 15
MINUTES, HOLD LIDS APART. GET IMMEDIATE MEDICAL ATTENTION.
INHALED-REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT
BREATHING, OXYGEN IF BREATHING DIFFICULT.

Flash Point Method:PMCC
Flash Point:=246.1C, 475.F
Extinguishing Media:USE STANDARD FIREFIGHTING TECHNIQUE TO EXTINGUISH
FIRES INVOLVING THIS MATERIAL. USE WATER SPRAY, DRY CHEMICAL OR
CARBON DIOXIDE.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR FULL-FACE,
SELF-CONTAINED BREATHING APPARATUS AND IMPERVIOUS PROTECTIVE
CLOTHING. KEEP FIRE EXPOSED CONTAINERS COOL WITH WATER SPRAY TO
PREVENT RUPTURE. HIGH PRESSURE WATER HO SE MAY SPREAD PRODUCT
INCRESING CONTAMINATION OR FIRE HAZARD.
Unusual Fire/Explosion Hazard:AS IN ANY FIRE, PREVENT HUMAN EXPOSURE TO
FIRE, SMOKE, FUMES OR PRODUCT OF COMBUSTION. EVACUATE NONESSENTIAL
PERSONNEL FROM FIRE AREA. PRODUCT MAY SUPPORT COMBUSTION AND
DECOMPOSE TO GIVE OFF TOXIC M ATERIALS SUCH AS PHOSPHORIC OXIDES.

Spill Release Procedures:MAKE SURE ALL PESONNEL INVOLVED IN THE SPILL
CLEANUP FOLLOW GOOD INDUSTRIAL HYGIENE PRACTICES. ANY PERSON
ENTERING EITHER A SPILL AREA OR AN AREA OF UNKNOWN CONCENTRATION OF
A GAS, VAPOR OR DUST SHOUL D USE A POSITIVE PRESSURE,
SELF-CONTAINED BREATHING APPARATUS OR A POSITIVE PRESSURE,
AIR-SUPPLIED RESPIRATOR WITH ESCAPE PACK. "SEE OTHER INFORMATION"

Handling and Storage Precautions:CONTAINER SHOULD BE STORED IN COOL,
DRY, WELL-VENTILATED AREA AWAY FROM FLAMMABLE MATERIALS & SOURCES.
STORE AWAY FROM FOOD OR ANIMAL FEED. PREVENT DAMAGE TO OR LEAKAGE
FROM CONTAINER. AVOID STORAGE A T ELEVATED TEMPERATURES UNDER WET
ALKALINE CONDITION. PREVENT MOISTURE CONDENSATION IN CONTAINER.
Other Precautions:CARBON STEEL IS THE PREFERED MATERIAL OF CONSTRUCTION
FOR STORAGE CONTAINERS. THE MATERIAL IS COMMONLY SHIPPED IN UNLINED
TANK CARS, TANK TRUCKS & DRUMS. AT TEMPERATURES BELOW 40F (4.4C),
THE VISCOSIT Y IS SUCH THAT IMPROVED PUMPING RATED MAY BE ACHIEVED
BY WARMING. TEMPERATURES FROM 80-100F PROVIDE GOOD RATES OF FLOW.

Respiratory Protection:WHERE ADEQUATE VENTILATION IS NOT AVAILABLE, USE
NIOSH-APPROVED ORGANIC VAPOR RESPIRATORS WITH DUST, MIST, FUME
FILTERS. WHERE EXPOSURE POTENTIAL IS GREATER UDER CONDITIONS
NEEDING GREATER PROTECTION, USE AN AIR-SUPPLIED, POSITIVE-PRESSURE
RESPIRATOR.
Ventilation:WHERE ENGINEERING CONTROLS ARE INDICATED: LOCAL EXHAUST,
ENCLOSED SYSTEM, PROCESS ISOLATION, REMOTE CONTROL, ETC MAY BE
USED.
Protective Gloves:SKIN CONTACT SHOULD BE MINIMIZED THROUGH THE USE OF
GLOVES.
Eye Protection:SAFETY GLASSES, GOGGLES AND/OR A FACE SHIELD.
Other Protective Equipment:LONG SLEEVED CLOTHING SELECTED WITH REGARD
FOR USE CONDITION EXPOSURE POTENTIAL.
Work Hygienic Practices:UNPROTECTED SKIN EXPOSED TO VAPORS, AEROSOLS OR
MIST SHOULD BE THOROUGHLY WASHED AT THE END OF THE WORK SHIFT.
BEFORE EATING, HANDS & FACE SHOULD BE THOROUGHLY WASHED.
Supplemental Safety and Health
ALL FOOD SHOULD BE KEPT IN A SEPARATE AREA AWAY FROM THE STORAGE/USE
LOCATION. EATING, DRINKING & SMOKING SHOULD BE PERMITTED IN AREAS
WHERE THERE IS APOTENTIAL FOR SIGNIFICANT EXPOSURE TO THIS MATERI
AL.

HCC:T4
Melt/Freeze Pt:=-17.6C, 0.F
Decomp Temp:>352.C, 665.6F
Vapor Pres:<0.1 MMHG AT 100F
Spec Gravity:1.15
Viscosity:200-230SUS
Solubility in Water:LESS THAN 0.1 G/100 ML IN
Appearance and Odor:CLEAR, TRANSPARENT LIQUID WITH ESENTIALLY NO ODOR.

Stability Indicator/Materials to Avoid:YES
HYDROLYZES SLOWLY AT AMBIENT TEMPERATURES WHEN EXPOSED TO WET ALKALINE
OR ACIDIC CONDITIONS. HYDROLYZES AT TEMPERATURE CONDITIONS &
TEMPERATURES OF 150F OR GREATER WHEN EXPOSED TO MOISTURE.
Stability Condition to Avoid:STABLE AT TEMPERATURES BELOW 150 DEG F (66
DEG C). IN THE ABSENCE OF MOISTURE, IT IS STABLE TO MUCH HIGHER
TEMPERATURES.
Hazardous Decomposition Products:UPON HYDROLYSIS, PHENOL, SUBSTITUTED
PHENOLS ANARYL PHOSPHORIC ACIDS ARE FORMED. THIS PRODUCT IS NOT
SENSTITIVE TO PHYSICAL IMPACT.

Waste Disposal Methods:MATERIAL THAT CANNOT BE USED OR CHEMICALLY
REPROCESSED & EMPTY CONTAINERS SHOULD BE DISPOSED OF AT AN APPROVED
FACILITY IN ACCORDANCE WITH ANY APPLICABLE REGULATIONS. NOTE: STATE
& LOCAL REGULATIONS M AY BE MORE STRINGENT THAN FEDERAL.

Toxicological Information:THE ACUTE ORAL LD50 IS GREATER THAN 5,000
MG/KG IN BOTH MALE & FEMALE RATS. A SINGLE DOSE OF 5,000 MG/KG
PRODUCED A MILD TO MODERATE DECREASE IN PHYSICAL ACTIVITY, SEVERE
DIARRHEA, STAINS ON FUR & NO MORTAILITY IN MALE & FEMALE RATS.
SKIN CONTACT: THE ACUTE DERMAL LD50 IS GREATER THAN 2,000 MG/KG
PRODUCED A SLIGHT DECREASE IN PHYSICAL ACTIVITY, MILD DIARRHEA &
10% MORTAILITY. MILD IRRITANT TO RABB IT SKIN FOLLOWING A 24-HR
EXPOSURE. EYES: MILD IRRITANT TO RABBIT EYES. INHALATION: THE ACUTE
INHALATION LC50 IS GREATER THAN 3.1 MG/L IN BOTH MALE & FEMALE
RATS. A SINGLE 4-HR EXPOSURE PRODUCED RUFF LED FUR & NO MORTALITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.