Product ID:856 8792,CONC,KODAK FLEXICOLOR STABILIZER III AND(SEE SUPPL)
MSDS Date:10/12/2000
FSC:6750
NIIN:00-539-9540
Status Code:A
MSDS Number: CLDPK

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716-722-5151

Info Phone: 800- 242-2424

Preparer: NOT PROVIDED

Cage: 19139

EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES

ROCHESTER, NY 14650-3129 US

Telephone: 800-828-6203

Cage: 5K871

WATER

CAS: 7732-18-5

RTECS: ZC0110000

FORMALDEHYDE

CAS: 50-00-0

RTECS: LP8925000

OSHA PEL 0.75 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHANOL

CAS: 67-56-1

RTECS: PC1400000

OSHA PEL 260 MG/M3;200 PPM

ACGIH TLV: 262 MG/M3;200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

OCTYLPHENOXYPOLY(ETHOXYETHANOL)

CAS: 9036-19-5

RTECS: MD0907600

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

SODIUM ALKYL PHENOXY ETHER SULFATE

CAS: 9014-90-8

RTECS: TR1583700

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALATION: FORMALDEHYDE AT HIGH
CONCENTRATIONS MAY CAUSE SEVERE BURNING SENSATIONS OF NOSE, THROAT
WITH COUGHING, CHEST CONSTRICTION, HEADACHE, BRONCHOPNEUMONIA,
DYSPHAGIA, EDEMA, AND SPASMS. EYES: CAUSES BURNS. VAPOR
IRRITATING. SKIN: CAUSES IRRITATION, ALLERGIC SKIN REACTION.
INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE BURNS OF MOUTH,
ESOPHAGUS, STOMACH. RETINAL AND KIDNEY DAMAGE MAY ALSO OCCUR .
IMMEDIATE SEVERE ABDOMINAL PAIN OCCURS, OFTEN WITH VOMITING,
NAUSEA, DIARRHEA, DIZZINESS, UNCONSCIOUSNESS OR COMA, ANURIA,
CONVULSIONS, AND POSSIBLE DEATH. MAY CAUSE VISUAL DISTURBANCES OR
BLINDNESS .
Explanation of Carcinogenicity:INTERNATIONAL AGENCY FOR RESEARCH ON
CANCER (IARC) (FORMALDEHYDE): 2A - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH) (FORMALDEHYDE):
SUSPECTED HUMAN CARCINOGEN (A2) NATIONAL TOXI COLOGY PROGRAM (NTP)
(FORMALDEHYDE): ANTICIPATED CARCINOGEN (2) - OCCUPATIONAL SAFETY
AND HEALTH ADMINISTRATION (OSHA) (FORMALDEHYDE): POTENTIAL CANCER
HAZARD.
Effects of Overexposure:INHALATION: FORMALDEHYDE AT HIGH CONCENTRATIONS
MAY CAUSE SEVERE BURNING SENSATIONS OF NOSE, THROAT WITH COUGHING,
CHEST CONSTRICTION, HEADACHE, EDEMA, AND SPASMS. EYES: CAUSES
BURNS. VAPOR IRRITATIN G. SKIN: CAUSES IRRITATION, ALLERGIC SKIN
REACTION. INGESTION: MAY CAUSE BURNS OF MOUTH, ESOPHAGUS, STOMACH.
IMMEDIATE SEVERE ABDOMINAL PAIN OCCURS, OFTEN WITH VOMITING,
NAUSEA, DIARRHEA, DIZZINESS, U NCONSCIOUSNESS OR COMA, CONVULSIONS,
AND POSSIBLE DEATH.
Medical Cond Aggravated by Exposure: EXPOSURE TO FORMALDEHYDE MAY CAUSE
RESPIRATORY SENSITIZATION IN SOME INDIVIDUALS OR AGGRAVATE
PRE-EXISTING ASTHMATIC CONDITIONS.

First Aid:INHALATION: MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. GET
MEDICAL ATTENTION. EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR
AT LEAST 1 5 MINUTES. GET MEDICAL ATTENTION IMMEDIATELY. SKIN:
IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING. IF SKIN IRRITATION/AN ALLERGIC SKIN REACTION
DEVELOPS, GE T MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE
REUSE. INGESTION: DO NOT INDUCE VOMITING. GIVE VICTIM A GLASS OF
WATER. CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. NEVER
GIVE ANYTHING B Y MOUTH TO AN UNCONSCIOUS PERSON.

Flash Point:NONE
Extinguishing Media:WATER SPRAY CARBON DIOXIDE (CO2), DRY CHEMICAL,
ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE.

Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNT OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL C ONTAMINATION.
Neutralizing Agent:NOT PROVIDED

Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM
INCOMPATIBLE SUBSTANCES (SEE INCOMPATIBILITY SECTION) KEEP FROM
CONTACT WITH OXIDIZING MATERIALS.
Other Precautions:DO NOT BREATHE VAPOR AT CONCENTRATIONS GREATER THAN
THE EXPOSURE LIMITS. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. USE
WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING.

Respiratory Protection:IF FORMALDEHYDE IS EMITTED AT LEVELS REQUIRING
RESPIRATORY PROTECTION, WEAR: FULL FACEPIECE WITH CARTRIDGES OR
CANISTERS SPECIFICALLY APPROVED BY NIOSH FOR PROTECTION AGAINST
FORMALDEHYDE OR TYPE C AI R-SUPPLIED RESPIRATOR DEMAND TYPE, WITH
FULL FACEPIECE, HOOD, OR HELMET. OBSERVE OSHA STANDARD 29CFR
1910.134 AND 29CFR 1910.1048.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR NEOPRENE RUBBER, NITRILE RUBBER GLOVES.
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES) AND
FACE SHIELD.
Other Protective Equipment:CHEMICAL PROTECTIVE CLOTHING MADE OF
MATERIAL IMPERVIOUS TO FORMALDEHYDE AND USE OF OTHER PERSONAL
PROTECTIVE EQUIP. EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE
LIMITS. CONTD FROM PRODUCT ID: REPLENISHER/C-41.

HCC:T7
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:68F: 24MBAR (18 MMHG)
Vapor Density:0.6
Spec Gravity:1.02
pH:6.0
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID, COLORLESS, SLIGHT FORMALDEHYDE ODOR.
Percent Volatiles by Volume:80-85 WT
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG BASES, METAL SALTS,
HYDROXIDES.
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF NITROGEN, FORMALDEHYDE.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNT
OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW
LABEL WARNINGS EV EN AFTER CONTAINER IS EMPTIED.

Toxicological Information:EFFECTS OF EXPOSURE: GENERAL: CONCENTRATE:
CONTAINS METHANOL, INGESTION MAY CAUSE VISUAL DISTURBANCES OR
BLINDNESS. DATA FOR FORMALIN: ACUTE TOXICITY DATA:
ORAL LD-50 (RAT): 800 MG/K G DERMAL LD-50: 270 MG/KG SKIN
IRRITATION: MODERATE IRRITATION EYE IRRITATION: SEVERE
IRRITATION INHALATION LCLO (RAT): 250 PPM/4 HOUR(S),
FORMALDEHYDE GAS

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: >100.
DAPHNID EC50 MG/L: >100. ALGAL IC50 MG/L: NOT AVAILABLE.
ORGANICS READI LY DEGRADABLE (>70%): YES (14 DAYS). POTENTIAL
BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 143. BOD5
(APPROXIMATE G/L): 78. POTENTIAL TOXICITY: WASTE TREATMENT
MICROORGANISMS EC50 (MG/L): >100. SECONDARY WASTE TREATMENT, THIS
MATERIAL IS NOT EXPECTED TO CAUSE ADVERSE ENVIRONMENTAL EFFECTS.

Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY .

SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: FORMALDEHYDE, METHANOL
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: FORMALDEHYDE - MATERIAL(S) KNOWN TO
THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS:
NONE