Product ID:SULFURIC ACID, CONCENTRATE
MSDS Date:02/15/2000
FSC:NIIN:Submitter:D DG
Status Code:A
Kit Part:Y
MSDS Number: CLFSD

Emergency Phone: 716-226-6177

Info Phone: 800-727-4368

Preparer: MICHAEL RASZEJA

Cage: 04TG8

Telephone: (716) 359-2502

Cage: 63759

SULFURIC ACID

CAS: 7664-93-9

RTECS: WS5600000

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:NO DATA PROVIDED BY MANUFACTURER
Health Hazards Acute and Chronic:TARGET ORGANS: RESPIRATORY SYSTEM,
EYES, SKIN, TEETH. INGESTION CAN CAUSE MUCOUS MEMBRANE BURNS,
ABDOMINAL PAIN, RESPIRATORY DISTRESS, SHOCK, RENAL FAILURE &
LESIONS OR PERFORATIONS OF THE ESOPHAGUS & GASTROINTESTINAL TRACT.
CONCENTRATED SOLUTIONS ARE EXTREMELY CORROSIVE & MAY CAUSE SEVERE
SKIN BURNS. REPEATED CONTACT WITH DILUTE SOLUTIONS MAY CAUSE SKIN
IRRITATION & DERMATITIS. SEVERE DAMAGE TO THE EYES CAN OCCUR VERY
RAPIDLY AND CONCENTRATED SOLUTIONS MAY CAUSE TOTALLY IRREVERSIBLE
DAMAGE, COMPLETE CORNEAL OPACITY OR PERFORATION OF THE GLOBE.
INHALATION CAN CAUSE RESPIRATORY IRRITATION, BRO
NCHIOSENSITIZATION, ESOPHAGEAL EDEMA.
Explanation of Carcinogenicity:NO DATA PROVIDED BY MANUFACTURER
Effects of Overexposure:INGESTION CAN CAUSE MUCOUS MEMBRANE BURNS,
ABDOMINAL PAIN, RESPIRATORY DISTRESS, SHOCK, RENAL FAILURE &
LESIONS OR PERFORATIONS OF THE ESOPHAGUS & GASTROINTESTINAL TRACT.
CONCENTRATED SOLUTIONS ARE E XTREMELY CORROSIVE & MAY CAUSE SEVERE
SKIN BURNS. REPEATED CONTACT WITH DILUTE SOLUTIONS MAY CAUSE SKIN
IRRITATION & DERMATITIS. SEVERE DAMAGE TO THE EYES CAN OCCUR VERY
RAPIDLY AND CONCENTRATED SOLUT IONS MAY CAUSE TOTALLY IRREVERSIBLE
DAMAGE, COMPLETE CORNEAL OPACITY OR PERFORATION OF THE GLOBE.
INHALATION CAN CAUSE RESPIRATORY IRRITATION, BRONCHIOSENSITIZATION,
ESOPHAGEAL EDEMA.
Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY MANUFACTURER

First Aid:SKIN: FLUSH THOROUGHLY WITH WATER FOR 15 MINUTES WHILE
REMOVING CONTAMINATED CLOTHING. GET MEDICAL ATTENTION. INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK LARGE
QUANTITIES OF M ILK OR WATER. GET IMMEDIATE MEDICAL ATTENTION.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. EYE: FLUSH
THOROUGHLY WITH WATER FOR 15 MINUTES LIFTING UPPER AND LOWER
EYELIDS OCCASIONALLY. GET IMMEDIATE MEDICAL ATTENTION. INHALTION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION.
IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.

Flash Point:NON FLAMMABLE
Extinguishing Media:DRY CHEMICALS
Fire Fighting Procedures:FIRE INVOLVING SMALL AMOUNT OF COMBUSTIBLES
MAY BE SMOTHERED BY DRY CHEMICAL. USE WATER ON COMBUSTIBLES BURNING
IN VACINITY OF ACID BUT USE CARE AS WATER APPLIED TO ACID RESULTS
IN SEVERE GERERATION O F HEAT & MAY CAUSE BOILING OR SPLATTERING.
WEAR A NIOSH/MSHA APPROVED SCBA 7 FULL PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:SULFURIC ACID WILL NOT BURN BUT IS
CAPABLE OF IGNITING FNELY DIVIDED COMBUSTIBLE MATERIALS ON CONTACT.
MAY REACT VIOLENTLY WITH ORGANIC MATERIALS AND WATER WITH THE
EVOLUTION OF HEAT.

Spill Release Procedures:WEAR PROTECTIVE SAFETY EQUIPMENT AND CLOTHING.
DILUTE SPILL CAUTIOUSLY WITH 5 0R 6 VOLUMES OF WATER, NEUTRALIZE
GRADUALLY WITH SODA ASH OR LIME. DO NOT ALLOW UNNEUTRALIZED ACID TO
GET INTO SEWERS CONT AINING SULFIDES BECAUSE OF DANGER OF EVOLVING
HYDROGEN SULFIDE GAS.
Neutralizing Agent:NEUTRALIZE GRADUALLY WITH SODA ASH OR LIME.

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED WHEN NOT
IN USE. ABSORBS MOISTURE FROM THE AIR. STORE IN A COOL, DRY, WELL
VENTILATED PLACE AWAY FROM INCOMPATIBLE MATERIALS.
Other Precautions:DON'T WEAR CONTACT LENSES WHEN WORKING WITH
CHEMICALS. NEVER ADD WATER TO ACID SOLUTION. ALWAYS ADD THIS ACID
SOLUTION TO WATER. ADDITION OF WATER MAY RELEASE HEAT WHICH COULD
RESULT IN SPLATTERING. A LWAYS ADD SLOWLY IN SMALL AMOUNTS. NEVER
USE HOT WATER. REMOVE/WASH CONTAMINATED CLOTHING. KEEP OUT OF
REACH OF CHILDREN

Respiratory Protection:WEAR A NIOSH/MSHA APPROVED RESPIRATOR SUITABLE
FOR LEVEL OF EXPOSURE.
Ventilation:LOCAL EXHAUST/ MECHANICAL(GENERAL): RECOMMENDED.
Protective Gloves:RUBBER
Eye Protection:CHEMICAL SAFETY GOGGLES
Other Protective Equipment:GOGGLES, FACE SHIELD, LAB COAT AND APRON,
VENTIALTION HOOD, EYE WASH STATION, PROPER GLOVES, SAFETY SHOWER.
Work Hygienic Practices:REMOVE AND WASH CONTAMINATED CLOTHING.
Supplemental Safety and Health
PART OF KIT CONTAINING SERIAL NUMBERS: CLFRQ, CLFRS, CLFRV, CLFRZ,
CLFSB, CLFSC. NOTE( DLA-HMIS STAFF): KIT HCC BASED ON DLAI4145.11,
TABLE B-3 PRECEDENCE. HCC FOR THIS PART: C1.

HCC:F5
Vapor Pres:VARIABLE
Spec Gravity:1.4
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR TO SLIGHTLY CLOUDY OILY LIQUID; ODORLESS TO
SLIGHT PUNGENT ODOR
Percent Volatiles by Volume:0.20 WATER

Stability Indicator/Materials to Avoid:YES
WATER, MANY METALS AND STRONG ALKALI MATERIALS. CONTACT WITH OXIDIZERS
MAY CAUSE VIOLENT REACTION/EXPLOSION OR FORM UNSTABLE COMPOUNDS.
CONSULT WITH ORGANIC MATERIALS MAY RESULT IN HIGHLY EXOTHERMIC
REACTION. CONTACT WITH F
Stability Condition to Avoid:EXCESSIVE TEMPERATURE AND HEAT
Hazardous Decomposition Products:SULFUR TRIOXIDE AND OR SULFUR DIOXIDE.
TOXIC AND EXPLOSIVE HYDROGEN SULFIDE GAS.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS.

Toxicological Information:NO DATA PROVIDED BY MANUFACTURER

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO DATA PROVIDED BY MANUFACTURER

Transport Information:D.O.T.: SULFURIC ACID, 8, UN1830, PG II.

SARA Title III Information:NO DATA PROVIDED BY MANUFACTURER
Federal Regulatory Information:NO DATA PROVIDED BY MANUFACTURER
State Regulatory Information:NO DATA PROVIDED BY MANUFACTURER