Product ID:VOA CALIBRATION MIX #4, 30009, 30009-5XX, 30109
MSDS Date:07/29/1996
FSC:NIIN:Submitter:N EN
Status Code:A
Kit Part:Y
MSDS Number: CLFSS

RESTEK CORPORATION

110 BENNER CIRCLE
BELLEFONTE, PA 16823-8812
US

Emergency Phone: 814-353-1300

Info Phone: 814-353-1300

Cage: OJL17

RESTEK CORP

BELLEFONTE, PA 16823-8812 US

Telephone: 814-353-1300

Cage: OJL17

METHANOL

CAS: 67-56-1

RTECS: PC1400000

OSHA PEL 200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1,2-DICHLOROETHANE

CAS: 107-06-2

RTECS: KI0525000

OSHA PEL 1 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BROMOFORM

CAS: 75-25-2

RTECS: PB5600000

OSHA PEL 0.5 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,1,1-TRICHLOROETHANE

CAS: 71-55-6

RTECS: KJ2975000

OSHA PEL 350 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

STYRENE

CAS: 100-42-5

RTECS: WL3675000

OSHA PEL 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TRANS-1,2-DICHLOROETHENE

CAS: 156-60-5

RTECS: KV9400000

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CIS-1,2-DICHLOROETHENE

CAS: 156-59-2

RTECS: KV9420000

BROMODICHLOROMETHANE

CAS: 75-27-4

RTECS: PA5310000

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

DIBROMOCHLOROMETHANE

CAS: 124-48-1

RTECS: PA6360000

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

TRANS-1,3-DICHLOROPROPENE(E)

CAS: 10061-02-6

RTECS: UC8320000

CIS-1,3-DICHLOROPROPENE(Z)

CAS: 10061-01-5

RTECS: UC8325000

1,1,2,2-TETRACHLOROETHANE

CAS: 79-34-5

RTECS: KI8575000

OSHA PEL 1 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

TETRACHLOROETHYLENE

CAS: 127-18-4

RTECS: KX3850000

OSHA PEL 25 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXPOSURE CAN CAUSE
DROWSINESS AND INTOXICATION, HEADACHE, VISUAL DISTURBANCE LEADING
TO BLINDNESS, COUGHING AND SHORTNESS OF BREATH, COLLAPSE AND DEATH
AT HIGH CONCENTRATIONS. EYE CONTACT: LIQUID CAN CAUSE MODERATE
BURNING, WATERING, SWELLING, AND REDNESS. SKIN CONTACT: EXTENSIVE,
REPEATED AND/OR PROLONGED SKIN CONTACT CAN CAUSE BURNING, ITCHING,
REDNESS, OR BLISTERS. INGESTION: CAUSES BURNING OF THE
GASTROINTESTINAL TRACT AND TOXIC EFFECTS. SWALLOWING MORE THAN 2
OUNCES OF METHANOL CAN CAUSE DEATH.
Explanation of Carcinogenicity:1,2-DICHLOROETHANE, TETRACHLOROETHYLENE,
BROMODICHLOROMETHANE:NTP 9TH ANNUAL REPORT REASONABLY ANTICIPATED
TO BE HUMAN CARCINOGENS LIST. STYRENE: IARC GROUP 2B, VOL 60, PAGE
233, '94. 1,2-DICHLOROETHA NE: IARC GROUP 2B, VOL 71, PAGE 501,
'99. TETRACHLOROETHYLENE: IARC GROUP 2A, VOL 63, PAGE 159, '95.
BROMODICHLOROMETHANE: IARC GROUP 2B, VOL 71,PAGE 1295, '99.
Effects of Overexposure:MILD POISONING IS CHARACTERIZED BY FATIGUE,
NAUSEA, HEADACHE, AND DELAYED VISUAL BLURRING. MODERATE
INTOXICATION RESULTS IN SEVERE DEPRESSION. TEMPORARY OR PERMANENT
BLINDNESS MAY FOLLOW IN 2-6 DAYS. IN SEVERE POISONING, SYMPTOMS
PROGRESS TO RAPID, SHALLOW RESPIRATION, CYANOSIS, COMA,
HYPERTENSION, DILATED PUPILS, AND VISUAL DISTURBANCE. DEATH MAY
RESULT FROM RESPIRATORY FAILURE.
Medical Cond Aggravated by Exposure:DERMATITIS, DISEASES OF EYES,
LIVER, KIDNEYS, LUNGS, AND CARDIOVASCULAR SYSTEM.

First Aid:EYES: REMOVE CONTACT LENSES IF PRESENT. HOLD EYELIDS OPEN AND
IRRIGATE WITH LARGE VOLUME OF WATER FOR 15 MIN. SEEK MEDICAL
TREATMENT. SKIN: IMMEDIATELY WASH WITH SOAP AND WATER. CONTINUE
RINSING WITH LARGE VOLUME OF WATER FOR 15 MIN. REMOVE CONTAMINATED
CLOTHING. SEEK MEDICAL TREATMENT. INHALATION: IF INHALED, REMOVE TO
FRESH AIR. HAVE A TRAINED PERSON ADMINISTER OXYGEN AND CPR IF
NEEDED. CONTACT A PHYSICIAN IMMEDIATELY. INGESTION: INGESTION MAY
CAUSE BLINDNESS. CONTACT A POISON CONTROL CENTER FOR ASSISTANCE.
CONTACT A PHYSICIAN IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO A
VICTIM UNCONSCIOUS OR HAVING CONVULSIONS.

Flash Point Method:CC
Flash Point:=12.C, 53.6F
Autoignition Temp:=385.C, 725.F
Lower Limits:6.0%
Upper Limits:36.5%
Extinguishing Media:DRY CHEMICAL, CO2, ALCOHOL FOAM, WATER MIST OR FOG.
Fire Fighting Procedures:IN CASE OF FIRE, WEAR SELF-CONTAINED BREATHING
APPARATUS (NIOSH APPROVED) AND PROTECTIVE CLOTHING. HEAT MAY BUILD
PRESSURE AND RUPTURE CLOSED STORAGE CONTAINERS. KEEP FIRE-EXPOSED
CONTAINERS COOL WITH WATER SPRAY. MAY BURN WITH AN INVISIBLE
FLAME. MIXTURES WITH WATER AS LOW AS 21% BY (UNUSUAL FIRE &
EXPLOSION HAZARD)
Unusual Fire/Explosion Hazard:HAZARDOUS MIXTURES OF OTHER LIQUIDS,
SOLIDS, OR GASES: INCOMPLETE COMBUSTION CAN GENERATE CARBON
MONOXIDE AND OTHER TOXIC VAPORS SUCH AS FORMALDEHYDE. FIRE
FIGHTING PROCEDURE (CONT): VOLUME ARE STIL L FLAMMABLE. UNDER SOME
CIRCUMSTANCES CAN CORRODE CERTAIN METALS, INCLUDING ALUMIUM AND
ZINC, AND GENERATE HYDROGEN GAS.

Spill Release Procedures:WEAR PERSONAL PROTECTIVE EQUIPMENT. PROTECT
FROM IGNITION. ABSORB SMALL SPILLS ON PAPER, VERMICULITE, OR OTHER
ABSORBENT. COLLECT AND STORE IN CLOSED CONTAINER FOR DISPOSAL.

Handling and Storage Precautions:CONTAINS CARCINOGENS OR SUSPECTED
CARCINOGENS. AVOID ALL INHALATION AND CONTACT. KEEP IN A TIGHTLY
CLOSED CONTAINER AT ALL TIMES. PROTECT FROM TEMPERATURE EXTREMES
AND DIRECT SUNLIGHT. HANDLE WITH THE UTMOST CARE. STORE IN AN
EXPLOSION PROOF FREEZER AT -18C.
Other Precautions:THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE CANCER.

Respiratory Protection:FOLLOW NIOSH AND EQUIPMENT MANUFACTURER'S
RECOMMENDATIONS TO DETERMINE APPROPRIATE RESPIRATOR.
Ventilation:USE IN AN AREA PROVIDED WITH GENERAL AND LOCAL EXHAUST
VENTILATION MEETING OSHA REQUIREMENTS.
Protective Gloves:SOLVENT RESISTANT NEOPRENE, NITRILE, OR RUBBER.
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES .
Other Protective Equipment:PROTECTIVE CLOTHING MEETING LABORATORY
SAFETY REQUIREMENTS. EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA .
Supplemental Safety and Health
ADDITIONAL INFORMATION ON INGREDIENTS: % COMPOSITION: COMPONENTS ARE
CALCULATED ON A WEIGHT/VOLUME BASIS. WARNING: CONTAINS
1,1,1-TRICHLOROETHANE, A SUBSTANCE WHICH HARMS HUMAN HEALTH AND
ENVIRON MENT BY DESTROYING OZONE IN THE UPPER ATMOSPHERE.

Boiling Pt:=65.C, 149.F
Vapor Pres:97 MM HG @ 20C.
Solubility in Water:MISCIBLE.
Appearance and Odor:COLORLESS / ALCOHOL ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS AND REACTIVE METALS WHICH WILL DISPLACE
HYDROGEN.
Stability Condition to Avoid:HEAT, SPARKS, AND CONTACT WITH IGNITION
SOURCE.

Waste Disposal Methods:INCINERATE AT AN APPROVED FACILITY IN ACCORDANCE
WITH FEDERAL, STATE AND LOCAL REGULATIONS.

Toxicological Information:COMPONENTS LISTED AS CARCINOGENS OR POTENTIAL
CARCINOGENS: STYRENE 100-42-5 (IARC) RTECS# WL3675000.
1,2-DICHLOROETHANE 107-06-2 (NTP, IARC) RTECS# KI0525000.
TETRACHLOROETHYLENE 127-18-4 (NTP, IARC) RTECS# KX3850000.
BROMOFORM 75-25-2 (CA PROP 65) RTECS# PB5600000.
DIBROMOCHLOROMETHANE 124-48-1 (CA PROP 65) RTECS# PA63600000.
CIS-1,3-DICHLOROPROPANE 10061-01-5 (CA PROP 65).
TRANS-1,3-DICHLOROPROP ANE (CA PROP 65). CONSULT RTECS FOR
COMPLETE INFORMATION ON THE EFFECTS OF THESE COMPOUNDS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

State Regulatory Information:CALIFORNIA PROPOSITION 65: THIS PRODUCT
CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER: BROMOFORM, DIBROMOCHLOROMETHANE,
CIS-1,3-DICHLOROPROPENE(Z), TRANS-1,3-DICHLOROPROPENE( E).