Product ID:CARCB-ACTIVATOR COMP. B
MSDS Date:03/16/2001
FSC:8010
NIIN:01-260-0909
Status Code:A
MSDS Number: CLFZY

NILES CHEMICAL PAINT

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 616-683-3377

Info Phone: 616-683-3377/219-236-5856

Preparer: ERNEST CARTER

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

HOMOPOLYMER OF HDI

CAS: 28182-81-2

RTECS: NQ9170000

HEXAMETHYLENE DIISOCYANATE

ACGIH TLV: 0.02

BUTYL ACETATE

CAS: 123-86-4

RTECS: AF7350000

OSHA PEL 710 MG/M3;150 PPM

ACGIH TLV: 713 MG/M3;150 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

XYLENE

CAS: 1330-20-7

RTECS: ZE2100000

ACGIH TLV: 434 MG/M3;100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:NONE
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:NONE
Explanation of Carcinogenicity:CONTAINS <0.5% CRYSTALLINE SILICA
Effects of Overexposure:INHALATION: OVEREXPOSURE INCLUDE: HEADACHE,
NAUSEA, NARCOSIS, FATIGUE AND LOSS OF APPETITE, SKIN: SYMPTOMS OF
SKIN IRRITATION MAY BE REDDENING, SWELLING, RASH, SCALING, OR
BLISTERING, SOME PERSONS MAY DEVELOP SKIN SENSITIZATION FROM SKIN
CONTACT. EYE: LIQUID, AEROSOLS AND VAPORS OF THIS PRODUCT ARE
IRRITATING AND CAN CAUSE TEARING. REDDENING, AND SWELLING
ACCOMPANIED BY A STINGING SENSATION. INGES TION: CAN RESULT IN
IRRITATION AND POSSIBLE CORROSIVE ACTION IN THE MOUTH, STOMACH
TISSUE AND DIGESTIVE TRACT.
Medical Cond Aggravated by Exposure:ASTHMA AND OTHER RESPIRATORY
DISORDERS (BRONCHITIS, EMPHYSEMA, HYPERREACTIVITY), SKIN ALLERGIES,
ECZEMA.

First Aid:INHALATION: MOVE TO AN AREA FREE FROM RISK OF FURTHER
EXPOSURE.OBTAIN MEDICAL ATTENTION. SKIN CONTACT: WASH AFFECTED AREA
THOROUGHLY WITH SOAP AND WATER.GET MEDICAL ATTENTION. EYE CONTACT:
FLUSH WITH CLEAN LUKEWARM WATER (LOW PRESSURE) FOR AT LEAST 15
MINUTES, OCCASIONALLY LIFTING EYELIDS. REFER INDIVIDUALS TO A
PHYSICIAN. INGESTION: DO NOT INDUCE VOMITING. GIVE 1 TO 2 CUPS OF
MILK OR WATER TO DR INK.

Flash Point Method:SCC
Flash Point:=32.8C, 91.F
Autoignition Temp:Autoignition Temp Text:NONE
Lower Limits:1.0
Upper Limits:7.6
Extinguishing Media:DRY CHEMICAL, FOAM, ALCOHOL FOAM, CO2.
Fire Fighting Procedures:FULL EMERGENCY EQUIPMENT WITH SELF CONTAINED
BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING SHOULD BE WORN BY
FIRE FIGHTERS DURING A FIRE, HDI VAPORS AND OTHER IRRITATING,
HIGHLY TOXIC GASES MAY BE GENERATED BY THERMAL DECOMPOSITION OR
COMBUSTION. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND
OPEN FLAME,
Unusual Fire/Explosion Hazard:CLOSED CONTAINER MAY EXPLODE WHEN EXPOSED
TO EXTREME HEAT OR BURST WHEN CONTAMINATED WITH WATER CREATING
CARBON DIOXIDE, SOLVENT VAPORS MAY BE HEAVIER THAN AIR. STAGNANT
AIR MAY CAUSE VAPORS TO BUILD UP AND TRAVEL ALONG THE GROUND TO AN
IGNITION SOURCE WHICH MAY RESULT IN A FLASH BACK TO THE SOURCE OF
THE VAPORS.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION AND VENTILATE
AREA. DIKE OR IMPOUND SPILLED MATERIAL AND CONTROL FURTHER
SPILLAGE. COLLECT MATERIAL IN OPEN CONTAINERS TO A SAFE PLACE. WASH
DOWN SPILL AREA WITH DECONTA MINATION SOLUTIONS. RESPIRATORY
PROTECTION IS RECOMMENDED DURING SPILL CLEAN UP.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, AND OPEN
FLAME, GROUND CONTAINERS DURING STORAGE AND TRANSFER OPERATIONS.
STORE IN TIGHTLY CLOSED CONTAINERS TO PREVENT MOISTURE
CONTAMINATION.
Other Precautions:NONE

Respiratory Protection:A RESPIRATOR THAT IS RECOMMENDED OR APPROVED FOR
USE IN ISOCYANATE ENVIRONMENTS (AIR PURIFYING OR FRESH AIR
SUPPLIED) MAY BE NECESSARY.
Ventilation:EXHAUST VENTILATION SUFFICIENT TO KEEP THE AIRBORNE
CONCENTRATIONS OF HDI AND POLYISOCYANATE BELOW THEIR RESPECTIVE
TLV.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:SAFETY GLASSES, SPLASH GOGGLES, OR FACE SHIELD.
Other Protective Equipment:NONE
Work Hygienic Practices:PRECAUTIONS MUST BE TAKEN SO THAT PERSONS
HANDLING POLYISOCYANATE DO NOT BREATH THE VAPORS OR HAVE IT CONTACT
THE EYES OR SKIN.
Supplemental Safety and Health
NONE

Boiling Pt:=121.1C, 250.F
B.P. Text:250-289 DEG F
Melt/Freeze Pt:M.P/F.P Text:NONE
Decomp Temp:Decomp Text:NONE
Vapor Density:HEAVIER
Spec Gravity:1.061
VOC Grams/Liter:2.21
Viscosity:182
Evaporation Rate & Reference:SLOWER THAN AIR
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR TO PALE YELLOW LIQUID/SOLVENT ODOR
Percent Volatiles by Volume:30.31
Corrosion Rate:MINIMAL

Stability Indicator/Materials to Avoid:YES
NITRATES, STRONG OXIDIZERS, ALKALIES, ACIDS.
Stability Condition to Avoid:MOISTURE, HIGH TEMPERATURES.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, OXDES
OF NITROGEN, TRACES OF HCN AND HDI.
Conditions to Avoid Polymerization:MAY OCCUR AT TEMPERATURES OVER 400F
(204 C).

Waste Disposal Methods:WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH
FEDERAL, STATE, AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.