Product ID:STANNOUS CHLORIDE S4760
MSDS Date:09/26/1997
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CLGXW

Emergency Phone: 310-516-8000

Info Phone: 310-516-8000

Preparer: E. BRULL

Cage: 63415

Telephone: 310-516-8000

Cage: JO675

STANNOUS CHLORIDE. (CONSULT LOCAL AUTHORITIES FOR

CAS: 10025-69-1

RTECS: XP8850000

ACGIH TLV: 2 MG/M3 (1995)

LD50 LC50 Mixture:ORAL (RAT) LD50: ACUTE: 700 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: SLIGHTLY DANGEROUS TO DANGEROUS
IN CASE OF SKIN CONTACT (IRRITANT), EYE CONTACT (IRRITANT),
INGESTION, INHALATION. CORROSIVE TO EYES AND SKIN. THE AMOUNT OF
TISSUE DAMAGE DEPENDS ON LENGTH OF CONTACT. EYE CONTACT CAN RESULT
IN CORNEAL DAMAGE OR BLINDNESS. SKIN CONTACT CAN PRODUCE
INFLAMMATION AND BLISTERING. INHALATION OF DUST WILL PRODUCE
IRRITATION TO GASTRO-INTESTINAL OR RESPIRATORY TRA CT,
CHARACTERIZED BY BURNING, SNEEZING AND COUGHING. SEVERE
OVER-EXPOSURE CAN PRODUCE LUNG DAMAGE, CHOKING, UNCONSCIOUSNESS OR
DEATH. CHRONIC: VERY DANGEROUS IN CASE OF SKIN CONTACT (IRRITANT),
EYE CO NTACT (IRRITANT), (EFTS OF OVEREXPOS)
Explanation of Carcinogenicity:CARCINOGENIC EFFECTS: NOT AVAILABLE.
Effects of Overexposure:HEALTH HAZARD ACUTE/CHRONIC (CONT'D):
INHALATION. SLIGHTLY DANGEROUS IN CASE OF SKIN CONTACT
(SENSITIZER). THE SUBSTANCE IS TOXIC TO LUNGS, MUCOUS MEMBRANES.
TOXICITY OF PRODUCT TO REPRODUCTIVE SYSTEM : NOT AVAILABLE.
REPEATED OR PROLONGED EXPOSURE TO SUBSTANCE CAN PRODUCE TARGET
ORGANS DAMAGE. REPEATED EXPOSURE OF EYES TO A LOW LEVEL OF DUST CAN
PRODUCE EYE IRRITATION. REPEATED SKIN EXPOSURE CAN P RODUCE LOCAL
SKIN DESTRUCTION, OR DERMATITIS. REPEATED INHALATION OF DUST CAN
PRODUCE VARYING DEGREE OF RESPIRATORY IRRITATION OR LUNG DAMAGE.
REPEATED OR PROLONGED INHALATION OF DUST MAY LEAD TO CHRO NIC
RESPIRATORY IRRITATION.

First Aid:EYES: CHECK FOR AND REMOVE ANY CONTACT LENSES. DO NOT USE AN
EYE OINTMENT. SEEK MEDICAL ATTENTION. SKIN: IF THE CHEMICAL GOT
ONTO THE CLOTHED PORTION OF THE BODY, REMOVE THE CONTAMINATED
CLOTHES AS Q UICKLY AS POSSIBLE, PROTECTING YOUR OWN HANDS AND
BODY. PLACE THE VICTIM UNDER A DELUGE SHOWER. IF THE CHEMICAL
TOUCHES THE VICTIM'S EXPOSED SKIN, SUCH AS THE HANDS: GENTLY AND
THOROUGHLY WASH THE CON TAMINATED SKIN WITH RUNNING WATER AND
NON-ABRASIVE SOAP. BE PARTICULARLY CAREFUL TO CLEAN FOLDS,
CREVICES, CREASES & GROIN. IF IRRITATION PERSISTS, SEEK MEDICAL
ATTENTION. SERIOUS SKIN CONTACT: WASH WITH A DISINFECTANT (SEE
TOXICOLOGICAL).

Flash Point:NOT APPLICABLE.
Lower Limits:N/APPLICABLE
Upper Limits:N/APPLICABLE
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE .
NON-FLAMMABLE.
Fire Fighting Procedures:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT (FP N). PRODUCTS OF
COMBUSTION: NOT APPLICABLE. FLAMMABILITY OF THE PRODUCT:
NON-FLAMMABLE.
Unusual Fire/Explosion Hazard:RISKS OF EXPLOSION OF THE PRODUCT IN
PRESENCE OF MECHANICAL IMPACT OR STATIC DISCHARGE: NOT AVAIALBLE.
NO SPECIFIC INFORMATION IS AVAILABLE IN MANUFACTURER'S DATABASE
REGARDING THE PRODUCT'S RISKS OF EXPLOSION IN THE PRESENCE OF
VARIOUS MATERIALS. FIRE HAZARDS IN PRESENCE OF VARIOUS SUBSTANCES:
NOT APPLICABLE.

Spill Release Procedures:SMALL SPILL: USE APPROPRIATE TOOLS TO PUT THE
SPILLED SOLID IN CONVENIENT WASTE DISPOSAL CONTAINER. LARGE SPILL:
CORROSIVE SOLID. STOP LEAK IF WITHOUT RISK. DO NOT GET WATER INSIDE
CONTAINER. DO NOT T OUCH SPIILLED MATERIAL. USE WATER SPRAY TO
REDUCE VAPORS. PREVENT ENTRY INTO SEWERS, BASEMENTS OR CONFINED
AREAS; DIKE IF NEEDED. CALL FOR ASSISTANCE ON DISPOSAL. WEAR SPLASH
(OTHER INFO)

Handling and Storage Precautions:KEEP CONTAINER DRY. DO NOT BREATHE
DUST. NEVER ADD WATER TO THIS PRODUCT. IN CASE OF INSUFFICIENT
VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT. IF YOU FEEL
UNWELL, SEEK MEDICAL ATTENTION AND SHOW THE LABEL WHEN POSSIBLE.
AVOID CONTACT WITH SKIN AND EYES. STORAGE: MAY CORRODE (OTHER PREC)
Other Precautions:N/P. HANDLING/STORAGE (CONT'D): METALLIC SURFACES.
STORE IN A METALLIC OR COATED FIBREBOARD DRUM USING A STRONG
POLYETHYLENE INNER PACKAGE. CORROSIVE MATERIALS SHOULD BE STORED IN
A SEPARATE SAFETY S TORAGE CABINET/ROOM. SUGGESTED PROTECTIVE
CLOTHING MIGHT NOT BE SUFFICIENT; CONSULT SPECIALIST BEFOR E
HANDLING PRODUCT.

Respiratory Protection:VAPOR AND DUST RESPIRATOR. NIOSH APPROVED
RESPIRATOR OR EQUIVALENT. WEAR APPROPRIATE RESPIRATOR WHEN
VENTILATION IS INADEQUATE. A SELF CONTAINED BREATHING APPARATUS
SHOULD BE USED TO AVOID INHALATION OF PRODUCT.
Ventilation:USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER
ENGINEERING CONTROLS TO KEEP AIRBORNE LEVELS BELOW RECOMMENDED
EXPOSURE LIMITS. IF USER (SUPP SFTY)
Protective Gloves:IMPERVIOUS GLOVES ..
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES AND FULL
FACESHIELD .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR SYNTHETIC APRON. LARGE SPILLS: WEAR FULL
SUIT, BOOTS.
Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSING.
Supplemental Safety and Health
SUGGESTED PROTECTIVE CLOTHING MIGHT NOT BE SUFFICIENT; CONSULT A
SPECIALIST BEFORE HANDLING THIS PRODUCT. VENTILATION (CONT'D):
OPERATIONS GENERATE DUST, FUME OR MIST, USE VENTILATION TO KEEP
EXPOSUR E TO AIRBORNE CONTAMINANTS BELOW THE EXPOSURE LIMIT.

Boiling Pt:B.P. Text:DECOMPOSES.
Melt/Freeze Pt:=37.5C, 99.5F
Vapor Pres:NOT AVAILABLE.
Vapor Density:N/AVAIL.
Spec Gravity:2.71 (WATER=1)
pH:NOT AVAILABLE.
Solubility in Water:NOT AVAILABLE.
Appearance and Odor:SOLID. ODOR, TASTE AND COLOR: NOT AVAILABLE.

Stability Indicator/Materials to Avoid:YES
NO SPECIFIC INFORMATION IS AVAILABLE IN MANUFACTURER'S DATABASE
REGARDING REACTIVITY OF THIS MATERIAL IN PRESENCE OF VARIOUS OTHER
MATERIALS. CORROSIVITY: SLIGHTLY CORROSIVE IN PRESENCE OF ALUMINUM.
NON-CORROSIVE IN PRESENC
Stability Condition to Avoid:INSTABILITY TEMPERATURE: NOT AVAILABLE.
CONDITIONS OF INSTABILITY: NO ADDITIONAL REMARK.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL REGULATIONS . RECYCLE TO PROCESS, IF
POSSIBLE. CONSULT YOUR LOCAL OR REGIONAL AUTHORITIES.

Toxicological Information:ACUTE ORAL TOXICITY (LD50): 700 MG/KG (RAT).
MUTAGENIC EFFECTS: NOT AVAILABLE. TERATOGENIC EFFECTS: NOT
AVAILABLE. CARCINOGENIC EFFECTS: NOT AVAILABLE. CHRONIC EFFECTS ON
HUMAN: THE SUBSTANCE IS TOXIC TO LUNGS, MUCOUS MEMBRANES. TOXICITY
OF THE PRODUCT TO THE REPRODUCTIVE SYSTEM: NOT AVAILABLE. OTHER
TOXIC EFFECTS ON HUMANS: SLIGHTLY DANGEROUS IN CASE OF SKIN CONTACT
(IRRITANT), OF EYE CONTACT (IR RITANT), OF INGESTION, OF
INHALATION. FIRST AID (CONT'D): SOAP AND COVER THE CONTAMINATED
SKIN WITH AN ANTI-BACTERIAL CREAM. SEEK MEDICAL ATTENTION.
INHALATION: ALLOW THE VICTIM TO REST IN A WELL VEN TILATED AREA.
(ECOLOGICAL)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICITY, BOD5 AND COD: NOT AVAILABLE. PRODUCTS OF
BIODEGRADATION: SOME METALLIC OXIDES. TOXICITY OF THE PRODUCTS OF
BIODEGRADATION: THE PRODUCTS OF DEGRADATION ARE MORE TOXIC.
TOXICOLOGICAL (CONT' D): SEEK IMMEDIATE MEDICAL ATTENTION. SERIOUS
INHALATION: EVACUATE THE VICTIM TO A SAFE AREA AS SOON AS POSSIBLE.
LOOSEN TIGHT CLOTHING SUCH AS COLLAR, TIE, BELT, OR WAISTBAND. IF
BREATHING DIFFICULT , ADMINISTER OXYGEN. IF VICTIM IS NOT
BREATHING, PERFORM MOUTH-TO MOUTH RESUSCITATION. WARNING: MAY BE
DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION (SARA)

Transport Information:DOT CLASSIFICATION: DOT CLASS 8, CORROSIVE SOLID.
IDENTIFICATION: CORROSIVE SOLID, N.O.S. (STANNOUS CHLORIDE), UN
1759 I I I. SPECIAL PROVISIONS FOR TRANSPORT: NO ADDITIONAL
REMARKS. PHYSICAL/CHE MICAL (CONT'D): MOLECULAR WEIGHT: 225.63.
CRITICAL TEMPERATURE, VOLATILITY, ODOR THRESHOLD, WATER/OIL DIST.
COEFF., IONICITY (IN WATER), AND DISPERSION PROPERTIES: NOT
AVAILABLE.

SARA Title III Information:N/P. ECOLOGICAL (CONTD): WHEN THE INHALED
MATERIAL IS TOXIC, INFECTIOUS OR CORROSIVE. SEEK IMMEDIATE MEDICAL
ATTENTION. INGESTION: DO NOT INDUCE VOMITING. HAVE CONSCIOUS
PERSON DRINK SEVERAL GLASSES OF WATER OR MILK. SEEK IMMEDIATE
MEDICAL ATTENTION. SERIOUS INGESTION: DO NOT INDUCE VOMITING.
EXAMINE LIPS AND MOUTH TO ASCERTAIN WHETHER THE TISSUES ARE
DAMAGED, A POSSIBLE INDICATION THAT THE TOXI C MATERIAL WAS
INGESTED; THE ABSENCE OF SUCH SIGNS, HOWEVER, IS NOT CONCLUSIVE.
LOOSEN TIGHT CLOTHING SUCH AS COLLAR, TIE, BELT OR WAISTBAND. IF
THE VICTIM IS NOT BREATHING, PERFORM MOUTH-TO-MOUTH RES USCITATION.
SEEK MEDICAL ATTENTION.
Federal Regulatory Information:TSCA: ON THE TSCA LIST. OSHA: HAZARDOUS
BY DEFINTION OF HAZARDOUS COMMUNICATION STANDARD (29 CFR
1910.1200). CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA): THIS
PRODUCT IS ON THE DOMESTIC SUBSTANCES LI ST (DSL), AND IS
ACCEPTABLE FOR USE UNDER THE PROVISIONS OF CEPA. (CANADA) WHMIS
CLASS E: CORROSIVE SOLID. DSCL (EEC) :R22- HARMFUL IF INGESTED;
R37- IRRITATING TO RESPIRATORY SYSTEM; R42- MAY CAUSE S
ENSITIZATION BY INHALATION.
State Regulatory Information:STANNOUS CHLORIDE IS LISTED BY THE STATES
OF MASSACHUSETTS AND PENNSYLVANIA. CALIFORNIA PROPOSITION 65
WARNINGS: WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE CAN CER. CHEMICAL INGREDIENT REQUIRING
THIS WARNING: NONE. WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN
TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM. CHEMICAL INGREDIENT REQUIRING THIS WARNING:
NONE.