Product ID:863 8553,WKG SOL,KODAK RP X-OMAT LO FIXER AND REPLENISHER
MSDS Date:05/02/2000
FSC:6525
NIIN:01-098-5799
Status Code:A
MSDS Number: CLHHK

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716-722-5151

Info Phone: 800- 242-2424

Preparer: NOT PROVIDED

Cage: 19139

EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS

ROCHESTER, NY 14650-1115 US

Telephone: 716-722-5151/(800) 242-2424

Cage: 19139

AMMONIUM THIOSULFATE

CAS: 7783-18-8

RTECS: XN6465000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

WATER

CAS: 7732-18-5

RTECS: ZC0110000

SODIUM THIOSULFATE

CAS: 7772-98-7

RTECS: XN6476000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

ACETIC ACID

CAS: 64-19-7

RTECS: AF1225000

OSHA PEL 25 MG/M3;10 PPM

ACGIH TLV: 25 MG/M3;10 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

AMMONIUM BISULFITE

CAS: 10192-30-0

RTECS: WT3595000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SODIUM BISULFITE

CAS: 7631-90-5

RTECS: VZ2000000

OSHA PEL NOT PROVIDED

ACGIH TLV: 5 MG/M3

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION:
EXPECTED TO BE A LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL
HANDLING BY TRAINED PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF
HEATED, SULFITES MAY LIBERATE SULFUR D IOXIDE GAS. SULFUR DIOXIDE
GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR
HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING.
EYES: NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANS IENT IRRITATION.
SKIN: THIS MATERIAL HAS A LOW POTENTIAL TO CAUSE ALLERGIC SKIN
REACTIONS; HOWEVER, CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN
REPORTED. INGESTION: MAY BE HARMFUL IF SWALLOWED.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE):- INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH) (SODI UM BISULFITE): A4
- NOT CLASSIFIABLE AS A HUMAN CARCINOGEN - NATIONAL TOXICOLOGY
PROGRAM (NTP): NONE- OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
(OSHA):NONE
Effects of Overexposure:INHALATION: IN CONTACT WITH STRONG ACIDS OR IF
HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE
GAS IS IRRITATING TO THE RESPIRATORY TRACT. EYES: MAY CAUSE
TRANSIENT IRRITATION.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING,
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.

First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
ANY MATERIAL THAT CONTACTS THE EYE SHOULD BE WASHED OUT IMMEDIATELY
WITH WATER. G ET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN:
IMMEDIATELY REMOVE CONTAMINATED CLOTHING AND SHOES AND WASH WITH
SOAP AND PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING AND SHOES.
WASH CONTAMINATED CLOTH ING BEFORE REUSE. DESTROY OR THOROUGHLY
CLEAN CONTAMINATED SHOES. INGESTION: DRINK 1-2 GLASSES OF WATER.
SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.

Flash Point:NONE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL,
ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG REDUCING
AGENT. DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT.

Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNT OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL C ONTAMINATION.
Neutralizing Agent:NOT PROVIDED

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED TO
PREVENT THE LOSS OF WATER. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES.
KEEP AWAY FROM COMBUSTIBLE MATERIAL. REMOVE AND WASH CONTAMINATED
CLOTHING PROMPTLY.
Other Precautions:AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH
EYES AND PROLONGED OR REPEATED CONTACT WITH SKIN. USE WITH ADEQUATE
VENTILATION. WASH THOROUGHLY AFTER HANDLING.

Respiratory Protection:NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE
WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE
BEEN RELEASED. RESPIRATOR TYPE: ACID GAS. SEE STABILITY AND
REACTIVITY SECTION. IF RESP IRATORS ARE USED, A PROGRAM SHOULD BE
INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:FOR PROLONGED OR REPEATED SKIN, IMPERVIOUS GLOVES
SHOULD BE WORN.
Eye Protection:SAFETY GLASSES W/SIDE SHIELDS, GOGGLES.
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE EYE CONTACT. IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE SKIN CONTACT.
Supplemental Safety and Health
ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE. N/K =
UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT
DETERMINED. N/E = NOT ESTABLISHED.

HCC:C3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:68F: 24MBAR (18 MM HG)
Vapor Density:0.6
Spec Gravity:1.087
pH:4.3-4.4
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID. COLOR AND ODOR: NOT AVAILABLE.
Percent Volatiles by Volume:80-85 WT
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, BASES, SODIUM HYPOCHLORITE (BLEACH), STRONG OXIDIZING
AGENTS, COMBUSTIBLE MATERIAL, HALOGENATED MATERIALS. CONTACT WITH
BASE LIBERATES FLAMMABLE MATERIAL.
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:SULFUR DIOXIDE, AMMONIA,
CHLORAMINE.OXIDES OF NITROGEN, OXIDES OF SULFUR.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNT
OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW
LABEL WARNINGS EV EN AFTER CONTAINER IS EMPTIED.

Toxicological Information:EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO
BE A LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY
TRAINED PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF HEATED,
SULFITES MAY LIBERATE SULFUR D IOXIDE GAS. SULFUR DIOXIDE GAS IS
IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR
HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING.
EYES: NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANS IENT IRRITATION.
SKIN: THIS MATERIAL HAS A LOW POTENTIAL TO CAUSE ALLERGIC SKIN
REACTIONS; HOWEVER, CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN
REPORTED. INGESTION: MAY BE HARMFUL IF SWALLOWED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: >100.
DAPHNID EC50 MG/L: >100. ALGAL IC50 MG/L: >100. ORGANICS
READILY DEGRAD ABLE (>70%): YES (7 DAYS). POTENTIAL
BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 90. BOD5
(APPROXIMATE G/L): 70. POTENTIAL TOXICITY: WASTE TREATMENT
MICROORGANISMS EC50 (MG/L): >100. AFT ER DILUTION WITH A LARGE
AMOUNT OF WATER, FOLLOWED BY SECONDARY WASTE TREATMENT, THIS
MATERIAL IS NOT EXPECTED TO CAUSE ADVERSE ENVIRONMENTAL EFFECTS.

Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD
TIME), MONDAY THROUGH FR IDAY.

SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: AMMONIUM THIOSULFATE, AMMONI UM BISULFITE, AMMONIUM
ACETATE, AS SOURCES OF AQUEOUS AMMONIA.
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE