Product ID:502.2 CALIBRATION MIX #3, 30044, 30044-5XX, 30144
MSDS Date:08/29/1995
FSC:NIIN:Submitter:N EN
Status Code:A
Kit Part:Y
MSDS Number: CLHLN

RESTEK CORPORATION

110 BENNER CIRCLE
BELLEFONTE, PA 16823-8812
US

Emergency Phone: 814-353-1300

Info Phone: 814-353-1300

Cage: OJL17

RESTEK CORP

BELLEFONTE, PA 16823-8812 US

Telephone: 814-353-1300

Cage: OJL17

METHANOL

CAS: 67-56-1

RTECS: PC1400000

OSHA PEL 200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CIS-1,2-DICHLOROETHENE

CAS: 156-59-2

RTECS: KV9420000

1,1-DICHLOROPROPENE

CAS: 563-58-6

RTECS: UC8290000

1,2-DICHLOROPROPANE

CAS: 78-87-5

RTECS: TX9625000

OSHA PEL 75 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,1,2-TRICHLOROETHANE

CAS: 79-00-5

RTECS: KJ3150000

OSHA PEL 10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

DIBROMOCHLOROMETHANE

CAS: 124-48-1

RTECS: PA6360000

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,1,1,2-TETRACHLOROETHANE

CAS: 630-20-6

RTECS: KI8450000

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,2,3-TRICHLOROPROPANE

CAS: 96-18-4

RTECS: TZ9275000

OSHA PEL 10 PPM

BROMOCHLOROMETHANE

CAS: 74-97-5

RTECS: PA5250000

OSHA PEL 200 PPM

1,2-DICHLOROETHANE

CAS: 107-06-2

RTECS: KI0525000

OSHA PEL 1 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

DIBROMOMETHANE

CAS: 74-95-3

RTECS: PA7350000

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TETRACHLOROETHENE

CAS: 127-18-4

RTECS: KX3850000

OSHA PEL 25 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,2-DIBROMOETHANE

CAS: 106-93-4

RTECS: KH9275000

OSHA PEL 20 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

1,1,2,2-TETRACHLOROETHANE

CAS: 79-34-5

RTECS: KI8575000

OSHA PEL 1 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,2-DIBROMO-3-CHLOROPROPANE

CAS: 96-12-8

RTECS: TX8750000

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:CONTAINS 1,2 DIBROMO-3-CHLOROPROPANE
WHICH IS LISTED IN THE NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE
HAZARDS LIST. CONSULT APPROPRIATE HEALTH PROFESSIONALS CONCERNING
SAFE HANDLING & EXPOSURE INFO (FP N). INHALATION: EXPOSURE CAN
CAUSE DROWSINESS AND INTOXICATION, HEADACHE, VISUAL DISTURBANCE
LEADING TO BLINDNESS, COUGHING AND SHORTNESS OF BREATH, COLLAPSE
AND DEATH AT HIGH CONCENTRATIONS. EYE CO NTACT: LIQUID CAN CAUSE
MODERATE BURNING, WATERING, SWELLING, AND REDNESS. SKIN CONTACT:
EXTENSIVE, REPEATED AND / OR PROLONGED SKIN CONTACT CAN CAUSE
BURNING, ITCHING, REDNESS, OR BLISTERS. (SIGNS AN D SYMPTOMS OF
OVEREXPOSURE)
Explanation of Carcinogenicity:1,2-DIBROMO-3-CHLOROPROPANE,
1,2-DICHLOROETHANE, TETRACHLOROETHENE, 1,2-DIBROMOETHANE: NTP 9TH
ANNUAL REPORT REASONABLY ANTICIPATED TO BE HUMAN CARCINOGENS LIST.
1,2 DICHLOROETHANE: IARC GROUP 2B, VOL UME 71, PAGE 501, 1999.
1,2-DIBROMO-3-CHLOROPROPANE: IARC GROUP 2B,VOLUME 71, PAGE 479,
1999; OSHA REGULATED 29 CFR 1910.1044. (TOXICOLOGICAL)
Effects of Overexposure:MILD POISONING IS CHARACTERIZED BY FATIGUE,
NAUSEA, HEADACHE, AND DELAYED VISUAL BLURRING. MODERATE
INTOXICATION RESULTS IN SEVERE DEPRESSION. TEMPORARY OR PERMANENT
BLINDNESS MAY FOLLOW IN 2 - 6 DAYS . IN SEVERE POISONING, SYMPTOMS
PROGRESS TO RAPID, SHALLOW RESPIRATION, CYANOSIS, COMA,
HYPOTENSION, DIALATED PUPILS, AND VISUAL DISTURBANCE. DEATH MAY
RESULT FROM RESPIRATORY FAILURE. HEALTH HA ZARDS ACUTE AND
CHRONIC (CONT): INGESTION: CAUSES BURNING OF THE GASTROINTESTINAL
TRACT AND TOXIC EFFECTS. SWALLOWING MORE THAN 2 OUNCES OF METHANOL
CAN CAUSE DEATH. CANCER HAZARD.
Medical Cond Aggravated by Exposure:DERMATITIS, DISEASES OF EYES,
LIVER, KIDNEYS, LUNGS, AND CARDIOVASCULAR SYSTEM.

First Aid:EYES: REMOVE CONTACT LENSES IF PRESENT. HOLD EYELIDS OPEN AND
IRRIGATE WITH LARGE VOLUME OF WATER FOR 15 MIN. SEEK MEDICAL
TREATMENT. SKIN: IMMEDIATELY WASH WITH SOAP AND WATER. CONTINUE
RINSING WITH LARGE VOLUME OF WATER FOR 15 MIN. REMOVE CONTAMINATED
CLOTHING. SEEK MEDICAL TREATMENT. INHALATION: IF INHALED, REMOVE TO
FRESH AIR. HAVE A TRAINED PERSON ADMINISTER OXYGEN AND CPR IF
NEEDED. CONTACT A PHYSICIAN IMMEDIATELY. INGESTION: INGESTION MAY
CAUSE BLINDNESS. CONTACT A POISON CONTROL CENTER FOR ASSISTANCE.
CONTACT A PHYSICIAN IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO A
VICTIM UNCONSCIOUS OR HAVING CONVULSIONS.

Flash Point Method:CC
Flash Point:=12.C, 53.6F
Autoignition Temp:=385.C, 725.F
Lower Limits:6.0%
Upper Limits:36.5%
Extinguishing Media:DRY CHEMICAL, CO2, ALCOHOL FOAM, WATER MIST OR FOG.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT . HEAT MAY BUILD PRESSURE
AND RUPTURE CLOSED STORAGE CONTAINERS. KEEP FIRE-EXPOSED CONTAINERS
COOL WITH WATER SPRAY. MAY BURN WITH AN INVISIBLE FLAME. MIXTURES
WITH WATER AS LOW AS 21% BY VOLUME (UNUSUAL FIRE & EXPLOSION
HAZARD)
Unusual Fire/Explosion Hazard:HAZARDOUS MIXTURES OF OTHER LIQUIDS,
SOLIDS, OR GASES: INCOMPLETE COMBUSTION CAN GENERATE CARBON
MONOXIDE AND OTHER TOXIC VAPORS SUCH AS FORMALDEHYDE. FIRE
FIGHTING PROCEDURES (CONT): ARE STIL L FLAMMABLE. UNDER SOME
CIRCUMSTANCES CAN CORRODE CERTAIN METALS, INCLUDING ALUMIUM AND
ZINC, AND GENERATE HYDROGEN GAS.

Spill Release Procedures:WEAR PERSONAL PROTECTIVE EQUIPMENT. PROTECT
FROM IGNITION. ABSORB SMALL SPILLS ON PAPER, VERMICULITE, OR OTHER
ABSORBENT. COLLECT AND STORE IN CLOSED CONTAINER FOR DISPOSAL.

Handling and Storage Precautions:CONTAINS CARCINOGENS OR SUSPECTED
CARCINOGENS. AVOID ALL INHALATION AND CONTACT. KEEP IN A TIGHTLY
CLOSED CONTAINER AT ALL TIMES. PROTECT FROM TEMPERATURE EXTREMES
AND DIRECT SUNLIGHT. HANDLE WITH THE UTMOST CARE. STORE IN AN
EXPLOSION PROOF FREEZER AT -18C.
Other Precautions:VARIOUS GOVERNMENT AGENCIES (I.E., DEPARTMENT OF
TRANSPORTATION, OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION,
ENVIRONMENTAL PROTECTION AGENCY, AND OTHERS) MAY HAVE SPECIFIC
REGULATIONS CONCERNING TH E TRANSPORTATION, HANDLING, STORAGE OR
USE OF THIS PRODUCT WHICH MAY NOT BE CONTAINED HEREIN. (OTHER
INFORMATION)

Respiratory Protection:FOLLOW NIOSH AND EQUIPMENT MANUFACTURER'S
RECOMMENDATIONS TO DETERMINE APPROPRIATE RESPIRATOR.
Ventilation:USE IN AN AREA PROVIDED WITH GENERAL AND LOCAL EXHAUST
VENTILATION MEETING OSHA REQUIREMENTS.
Protective Gloves:SOLVENT RESISTANT NEOPRENE, NITRILE, OR RUBBER.
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES .
Other Protective Equipment:PROTECTIVE CLOTHING MEETING LABORATORY
SAFETY REQUIREMENTS. EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA .
Supplemental Safety and Health
ADDITIONAL INFORMATION ON INGREDIENTS: % COMPOSITION: COMPONENTS ARE
CALCULATED ON A WEIGHT/VOLUME BASIS.

Boiling Pt:=65.C, 149.F
Vapor Pres:97 MM HG @ 20C.
Solubility in Water:MISCIBLE.
Appearance and Odor:COLORLESS/ ALCOHOL ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS AND REACTIVE METALS WHICH WILL DISPLACE
HYDROGEN.
Stability Condition to Avoid:HEAT, SPARKS, AND CONTACT WITH IGNITION
SOURCE.

Waste Disposal Methods:INCINERATE AT AN APPROVED FACILITY IN ACCORDANCE
WITH FEDERAL, STATE AND LOCAL REGULATIONS.

Toxicological Information:CONSULT RTECS FOR COMPLETE INFORMATION ON THE
EFFECTS OF THE COMPOUNDS LISTED AS CARCINOGENS OR POTENTIAL
CARCINOGENS. EXPLANATION OF CARCINOGENICITY (CONT): 1,2
DIBROMOETHANE: IARC GROUP 2A, VOLUME 71, PAGE 641, 1999.
TETRACHLOROETHYLENE: IARC GROUP 2A, VOLUME 63, PAGE 159, 1995.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

State Regulatory Information:CALIFORNIA PROPOSITION 65: THIS PRODUCT
CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OF OTHER REPRODUCTIVE HARM:
1,2-DICHLOROPROPANE, 1,1,2-TRICHLOROETHANE , DIBROMOCHLOROMETHANE,
1,2,3-TRICHLOROPROPANE, 1,1,2,2-TETRACHLOROETHANE.