Product ID:7280, SIFCO DALIC SOLUTION AERONIKL 250 (SULFAMATE NICKEL)
MSDS Date:03/13/2000
FSC:6850
NIIN:01-292-9738
Status Code:A
MSDS Number: CLKZB

SIFCO SELECTIVE PLATING DIV OF SIFCO INDUSTRIES INC.

5708 SCHAAF ROAD
CLEVELAND, OH 44131-1394
US

Emergency Phone: 800-424-9300 216-524-0099

Info Phone: -6331

Preparer: WERNER A. EHRENSCHEIDER

Cage: 11924

SIFCO SELECTIVE PLATING DIV OF SIFCO INDUSTRIES INC.

CLEVELAND, OH 44131-1394 US

Telephone: -6331

Cage: 11924

NICKEL (SARA 313) (CERCLA)

CAS: 7440-02-0

RTECS: QR5950000

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3; 9596

SULFAMIC ACID

CAS: 5329-14-6

RTECS: WO5950000

BORIC ACID

CAS: 10043-35-3

RTECS: ED4550000

OSHA PEL 10 MG BORATES/M3

ACGIH TLV: 5 MG BORATES/M3

WATER

CAS: 7732-18-5

RTECS: ZC0110000

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:TARGET ORGANS: SKIN,EYES,NASAL CAVITY,
LUNGS, KIDNEYS AND LIVER. EYE: CAUSES EYE IRRITATION, BURNS
POSSIBLE. SKIN CONTACT: MAY CAUSE SKIN IRRITATION. MAY CAUSE SKIN
SENSITIZATION, AND ALLERGIC REACTIO N (NICKEL RASH). INHALATION:
MAY CAUSE SNEEZING, NASAL DISCHARGE, COUGHING, HEADACHES,
DIZZINESS, NAUSEA, FATIGUE OR DIFFICULTY IN BREATHING. IRRITATING
TO THE EYES, NOSE THROAT, AND LUNGS. INGESTION: MAY CAUSE BURNS TO
MUCOUS MEMBRANES. CAN IRRITATE MOUTH, THROAT, AND STOMACH. MAY
CAUSE LIVER DAMAGE WITH JAUNDICE,KIDNEY AND GASTROINTESTINAL
DAMAGE.
Explanation of Carcinogenicity:NICKEL COMPOUNDS ARE LISTED BY IARC &
NTP AS CARCINOGENS. MFR LISTS AS OSHA REGULATED
Effects of Overexposure:EYE: CAUSES EYE IRRITATION, BURNS POSSIBLE.
SKIN CONTACT: MAY CAUSE SKIN IRRITATION. MAY CAUSE SKIN
SENSITIZATION, AND ALLERGIC REACTION (NICKEL RASH). INHALATION: MAY
CAUSE SNEEZING, NASAL DISCHARGE, COUGHING, HEADACHES, DIZZINESS,
NAUSEA, FATIGUE OR DIFFICULTY IN BREATHING. IRRITATING TO THE EYES,
NOSE THROAT, AND LUNGS. INGESTION: MAY CAUSE BURNS TO MUCOUS
MEMBRANES. CAN IRRITATE MOUTH, THROAT, AND STOMACH. MAY CAUSE
LIVER DAMAGE WITH JAUNDICE,KIDNEY AND GASTROINTESTINAL DAMAGE.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN & EYE CONDITIONS,
RESPIRATORY SYSTEM DISORDERS, PRE-EXISTING SENSITIZATION TO NICKEL.

First Aid:EYES: HOLD EYELIDS APART AND FLUSH EYES WITH PLENTY OF WATER
AT LEAST 15 MINUTES. SKIN: IMMEDIATELY FLUSH SKIN WITH PLENTY OF
WATER AT LEAST 15 MINUTES REMOVING CONTAMINATED CLOTHING AND SHOES.
THOROU GHLY DECONTAMINATE (OR DISCARD) CLOTHING AND SHOES.
INHALATION: REMOVE TO FRESH AIR. LAY VICTIM DOWN, LEGS RAISED.
LOOSEN TIGHT CLOTHING, COVER WITH BLANKET. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRAT ION. IF BREATHING DIFFICULT, GIVE OXYGEN.
INGESTION: DO NOT INDUCE VOMITING, UNLESS ADVISED BY EMS. GIVE
VICTIM LARGE QUANTITIES OF WATER OR MILK. GIVE MILK OF MAGNESIA OR
FRESH EGGS. NEVER GIVE ANYT HING BY MOUTH TO UNCONSCIOUS PERSON.

Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:N.A.
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:ALL.
Fire Fighting Procedures:NIOSH/MSHA APPROVED POSITIVE-PRESSURE
SELF-CONTAINED BREATHING APPARATUS. STRUCTURAL FIRE FIGHTERS
PROTECTIVE CLOTHING MAY NOT PROVIDE ADEQUATE PROTECTION.
Unusual Fire/Explosion Hazard:CONTAINERS CAN BUILD-UP PRESSURE & BURST
IF EXPOSED TO HEAT (FIRE). CONTACT WITH METALS MAY FORM FLAMMABLE
HYDROGEN GAS.WATER RUNOFF CAN CAUSE ENVIRONMENTAL DAMAGE. DIKE AREA
FOR LATER DISPOSAL.

Spill Release Procedures:ISOLATE & DENY ENTRY. DO NOT TOUCH SPILLED
MATERIAL. ELIMINATE ALL SOURCES OF IGNITION. NOTIFY FACILITY
EMERGENCY COORDINATOR. PROVIDE MAXIMUM VENTILATION. KEEP PRODUCT
OUT OF SURFACE WATERS/SEWERS. WEAR PROPER PERSONAL PROTECTIVE
EQUIPMENT (PPE). CAREFULLY MOP UP OR VACUUM INTO PLASTIC CONTAINER.
RELEASE OF REPORTABLE QUANTITY (RQ) REQUIRES NOTIFICATION OF PROPER
AUTHORITIES.
Neutralizing Agent:SODA ASH AND CRUSHED LIMESTONE.

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED IN
UPRIGHT POSITION. STORE AT 60-90F AWAY FROM INCOMPATIBLE MATERIALS
AND PHYSICAL HAZARDS. DO NOT REMOVE OR DEFACE LABELS. USE "BUDDY
SYSTEM" WHEN WORKING WITH CHEMICALS . DO NOT GET IN EYES, ON SKIN,
ON CLOTHING. DO NOT BREATH VAPOR, MIST OR GAS.
Other Precautions:USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. TRIPLE RINSE CONTAINER CLEAN BEFORE DISCARDING. PUT
NOTHING ELSE IN THIS CONTAINER.

Respiratory Protection:IF ENGINEERING CONTROLS ARE NOT FEASIBLE, THE
RESPIRATORY PROTECTION PROGRAM MUST COMPLY WITH OSHA'S 29 CFR
1910.134, 30 CFR 11 AND ANSI Z88.2 REQUIREMENTS.
Ventilation:LOCAL EXHAUST IS REQUIRED TO MEET THE PERMISSABLE EXPOSURE
LIMIT (PEL) DURING THE USE OF THIS PRODUCT.
Protective Gloves:NITRILE, NEOPRENE, VINYL, LATEX.
Eye Protection:FACE SHIELD AND SAFETY GLASSES W/SIDE SHIELDS OR
SPLASH-PROOF CHEMICAL GOGGLES.
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, WASHING
FACILITIES NEAR WORK AREA, IMPERVIOUS BOOTS, APRON, PROTECTIVE
CLOTHING AS REQUIRED BY JOB CONDITIONS.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

HCC:C1
Boiling Pt:=100.C, 212.F
Melt/Freeze Pt:<0.C, 32.F
Spec Gravity:1.320 -1.340
pH:1.2 - 1.6
Evaporation Rate & Reference:<1 (ETHYL ETHER=1)
Solubility in Water:COMPLETE
Appearance and Odor:DARK GREEN LIQUID; SLIGHT ODOR.

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH REACTIVE METALS, STRONG BASES, OXIDIZERS, CYANIDES,
SULFIDES.
Stability Condition to Avoid:STABLE UNDER NORMAL AMBIENT CONDITIONS.
Hazardous Decomposition Products:HYDROGEN GAS, OXIDES OF SULFUR (SOX) &
NITROGEN (NOX), NICKEL, BORON.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:SHIP TO APPROVED TREATMENT/DISPOSAL FACILITY.
DISPOSE OF IAW LOCAL, STATE AND FEDERAL REGULATIONS. EPA/RCRA WASTE
NUMBER: D002. FOLLOW APPLICABLE REGULATIONS FOR DISPOSAL OF EMPTY
CONTAINERS AND RINSA TE. DISPOSAL INFORMATION APPLIES TO MATERIAL
AS MANUFACTURERED. CONTAMINATION MAY AFFECT DISPOSAL RE QUIREMENTS.
RESPONSIBILITY PROPER WASTE DISPOSAL.

Toxicological Information:NOT AVAILABLE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NOT AVAILABLE.

Transport Information:DOT, IATA, ICAO, IMO DESCRIPTION: PROPER SHIPPING
NAME: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (CONTAINS
SULFAMIC ACID); HAZARD CLASS: 8; IDENTIFICATION NUMBER: UN3264;
PACKAGING GROUP (PG): III ; LABEL REQUIREMENTS: 8 - CORROSIVE; UNIT
CONTAINER: 4 LITER POLYETHYLENE BOTTLE; PACKAGING MEETS PERFORMANCE
ORIENTED PACKAGING REQUIREMEMNTS. REPORTABLE QUANTITY (RQ): NOT
APPLCABLE. 1996 NAERG GUID E #: 154. NOTE: SAMMS-CTDF HAS THE
FOLLOWING PROPER SHIPPINGS DATA (CONTRACT REQUIREMENT?): CORROSIVE
LIQUIDS, N.O.S. (SULFAMATE) UN1760. DLA-HMIS WILL ATTEMPT TO CHANGE
THIS TO MORE DEFINITIVE/UP-TO- DATE PSN.

SARA Title III Information:PRODUCT CONTAINS A TOXIC CHEMICAL OR
CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF
TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF
1986 AND 40 CFR PART 372, IF SPE CIFIED ANNUAL THREASHOLDS ARE MET
OR EXCEEDED: NICKEL COMPOUNDS, AS NI, CAS# 7440-02-0, 10%. EPCRA
HAZARD CATAGORIES: IMMEDIATE (ACUTE) HEALTH: YES; DELAYED (CHRONIC)
HEALTH: YES; FIRE: NO; SUDDEN REL ASE OF PRESSURE: NO; REACTIVITY:
NO. EPCRA THRESHOLD PLANNING QUANTITY (TPQ): NOT APPLICABLE.
Federal Regulatory Information:TSCA: ALL INGREDIENTS OF THIS PRODUCT
ARE LISTED UNDER THE TOXIC SUBSTANCES CONTROL ACT (TSCA). ODS
CERTIFICATION: THIS PRODUCT DOES NOT CONTAIN AND IS NOT
MANUFACTURED WITH OZONE DEPLETING SUBSTANCES (ODS). VOC
CERTIFICATION: THIS PRODUCTDOES NOT CONTAIN ANY VOLATILE ORGANIC
COMPOUNDS (VOC). CERCLA: RELEASE REPORTABLE QUANTITY(RQ): NOT
APPLICABLE. EXTREMELY HAZARDOUS SUBSTANCE: NONE. PCB CERTIFIC
ATION: THIS PRODUCT DOES NOT CONTAIN ANY PLYCHLORINATED BIPHENYLS
(PCB).
State Regulatory Information:WARNING! THIS PRODUCT DOES CONTAINS
DETECTABLE AMOUNTS OF CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.