Product ID:H-640
MSDS Date:11/13/1995
FSC:NIIN:Submitter:F BT
Status Code:A
MSDS Number: CLLWL

CALGON CORP

RT 60 AND CAMPBELLS RUN RD
PITTSBURGH, PA 15230-1346
US

Emergency Phone: 412-494-8000

Info Phone: 412-494-8000

Preparer: P.J. MALONEY

Cage: 86035

CALGON CORP

1346 PITTSBURGH, PA 15230-1346 US

Telephone: 412-494-8000

Cage: 86035

TERBUTHYLAZINE

CAS: 5915-41-3

OSHA PEL NONE ESTABLISHED

ACGIH TLV: NONE ESTABLISHED

ETHYLENE GLYCOL

CAS: 107-21-1

RTECS: KW2975000

OSHA PEL C50 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAUTION! HARMFUL IF SWALLOWED OR
ABSORBED THROUGH SKIN. LONG TERM EXPOSURE MAY CAUSE LYMPHATIC
ORGAN DAMAGE AND/OR OTHER ADVERSE EFFECTS.
Explanation of Carcinogenicity:TERBUTHYLAZINE HAS BEEN TESTED IN THE
RAT,RABBIT OR MOUSE FOR PERIODS FROM 4 WEEKS TO 2 YEARS BY EITHER
THE ORAL OR DERMAL ROUTES.SOME OF THESE STUDIES SHOWED TOXIC
EFFECTS IN LYMPHATIC ORGANS.THE ORA L NO OBSERVABLE EFFECT LEVEL IN
THE RAT WAS 8 MG/KG/DAY OVER 4 WEEKS AND 0.35 MG/KG/DAY OVER 2
YEARS AND 17MG/KG/DAY OVER 2 YEARS IN THE MOUSE.
Effects of Overexposure:EYE:THIS PRODUCT WOULD NOT BE EXPECTED TO
PRODUCE SIGNIFICANT IRRITATION UPON CONTACT WITH THE EYE.
SKIN:REPEATED EXPOSURES CAN CAUSE PROBLEMS. INGESTION:THIS PRODUCT
WOULD BE EXPECTED TO BE MODERATEL Y TOXIC BY INGESTION. INGESTION
OF LARGEVOLUMES OF ETHYLENE GLYCOL MAY RESULT IN CENTRAL NERVOUS
SYSTEM DEPRESSION AND KIDNEY DAMAGE. CARDIAC FAILURE AND PULMONARY
EDEMA MAY DEVELOP. INHALATION:THIS P RODUCT IS NOT EXPECTED TO
PRESENT AND INHALATION HAZARD UNLESS MISTS OR VAPORS ARE GENERATED.
SIGNIFICANT AIR CONCENTRATIONS ARE NOT ACHIEVED UNLESS THE PRODUCT
IS HEATED.
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:EYE: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY
OF WATER. SEEK MEDICAL AID IF IRRITATION PERSISTS. SKIN: FLUSH SKIN
WITH PLENTY OF WATER OR WASH WITH MILD SOAP AND WATER. INGESTION:
IF SWA LLOWED, CALL A PHYSICIAN OR A POISON CONTROL CENTER. DO NOT
INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION:
IF INHALED AND IRRITATION OR DIFFICULTY IN BREATHING OCCURS,
REMOVE TO FRESH AIR. SEEK MEDICAL AID IF IRRITATION OR DISCOMFORT
PERSISTS.

Flash Point:>93.3C, 200.F
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, FOAM, CARBON DIOXIDE.
Fire Fighting Procedures:EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL
FIRE. A SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING
ARE ESSENTIAL.
Unusual Fire/Explosion Hazard:PRODUCT EMITS TOXIC GASES UNDER FIRE
CONDITIONS.

Spill Release Procedures:WEARING APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT, CONTAIN SPILL, COLLECT ONTO INERT ABSORBENT AND PLACE
INTO SUITABLE CONTAINER. CONTROL RUNOFF AS IT MAY INJURE LAWNS,
TREES, SHRUBS, AND OTHER PLANTS .

Handling and Storage Precautions:IT IS A VIOLATION OF FEDERAL LAW TO
USE THIS PRODUCT IN A MANNER INCONSISTENT WITH ITS LABELING. AVOID
CONTACT WITH EYES,SKIN,AND CLOTHING. DO NOT CONTAMINATE
WATER,FOOD,OR FEED BY STORAGE. DO NOT EXP OSE TO EXTREME
TEMPERATURES. AVOID BREATHING VAPOR OR MIST. USE WITH ADEQUATE
VENTILATION.

Respiratory Protection:IF AIRBORNE CONCENTRATIONS EXCEED PUBLISHED
EXPOSURE LIMITS, USE A NIOSH APPROVED RESPIRATOR IN ACCORDANCE WITH
OSHA RESPIRATORY PROTECTION REQUIREMENTS.
Ventilation:USE LOCAL EXHAUST VENTILATION AT ELEVATED TEMPERATURES OR
IF MISTS ARE GENERATED.
Protective Gloves:CHEMICAL RESISTANT GLOVES
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING
Supplemental Safety and Health
HMIS RATINGS: HEALTH=1, FLAMMABILITY=1, REACTIVITY=0 *THERE ARE
POTENTIAL CHRONIC HEALTH EFFECTS TO CONSIDER. % VOLATILES BY WT =
NOT DETERMINED

Boiling Pt:B.P. Text:NOT DETERMINED
Melt/Freeze Pt:=-2.2C, 28.F
Vapor Pres:0.12
Vapor Density:2.14
Spec Gravity:1.05-1.15
pH:7.0-9.0
Solubility in Water:MISCIBLE
Appearance and Odor:WHITE TO BEIGE, LOW VISCOSITYPASTE WITH SLIGHT
ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG BASES, ACIDS, AND OXIDIZERS.
Stability Condition to Avoid:AVOID HIGH TEMPERATURES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION OR COMBUSTION
MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN OXIDES, AND
SULFUR OXIDES. CHLORINE COMPOUNDS AND OTHER TOXIC SPECIES MAY ALSO
BE FORMED.

Waste Disposal Methods:RCRA STATUS:PRODUCT IS A PESTICIDE AND MUST BE
DISPOSED OF IN A MANNER APPROVED BY EPA RESOURCE CONSERVATION AND
RECOVERY ACT. PESTICIDE WASTES ARE ACUTELY HAZARDOUS. IMPROPER
DISPOSAL OF EXCESS PESTI CIDE,SPRAY MIXTURE,OR RINSATE IS A
VIOLATION OF FEDERAL LAW.

Toxicological Information:ORAL LD50 (RAT):1350 MG/KG;DERMAL LD50
(RABBIT):>4400 MG/KG TWO-YEAR STUDIES ON TERBUTHYLAZINE SHOWED A
SMALL INCREASED INCIDENCE OF MAMMARY TUMORS IN THE HIGH DOSE
FEMALES RATS WITH NO INCREASED TUM OR INCIDENCE IN THE MOUSE. THIS
DATA IS NOT CONSIDERED TO BE REVELANT TO HUMANS. IN ONE STUDY, WHEN
ETHYLENE GLYCOL WAS ADMINISTERED IN THE DIET AT DAILY DOSES UP TO
1.0 G/KG TO PREGNANT RATS, NO MATE RNAL TOXICITY, NO EMBRYOTOXICTY
NOR TERATOGENICITY WERE OBSERVED. IN A MORE RECENT STUDY, WHEN
ETHYLENE GLYCOL WAS ADMINISTERED BY GAVAGE AT DAILY DOSES OF 1.25
G/KG AND ABOVE TO PREGNANT RATS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:DO NOT DISCHARGE EFFLUENT CONTAINING THIS PRODUCT INTO
LAKES, STREAMS, PONDS, ESTUARIES, OCEANS, OR OTHER WATERS UNLESS IN
ACCORDANCE WITH THE REQUIREMENTS OF A NATIONAL POLLUTANT DISCHARGE
ELIMINATIO N SYSTEM PERMIT AND THE PERMITTING AUTHORITY HAS BEEN
NOTIFIED IN WRITING PRIOR TO DISCHARGE. DO NOT DISCHARGE EFFLUENT
CONTAINING THIS PRODUCT TO SEWER SYSTEMS WITHOUT PREVIOUSLY
NOTIFYING THE LOCAL SEWAGE TREATMENT PLANT AUTHORITY. FOR GUIDANCE
CONTACT YOUR STATE WATER BOARD OR REGIONAL OFFICE OF THE EPA.
INHIBITORY CONCENTRATION ON RESPIRATION OF AEROBIC WASTE WATER
BACTERIA: IC20, IC50, IC80>1 00 PPM .

SARA Title III Information:SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES:
THERE ARE NO SARA 302 EXTREMELY HAZARDOUS SUBSTANCES IN THIS
PRODUCT. SECTION 311 AND 312 HEALTH AND PHYSICAL HAZARDS:
IMMEDIATE=YES, DELAYED=YES, FIRE=NO, PRESSURE=NO, REACTIVITY=NO.
SECTION 313 TOXIC CHEMICALS: ETHYLENE GLYCOL
Federal Regulatory Information:OSHA HAZARD COMMUNICATION STATUS:
HAZARDOUS; TSCA: PESTICIDES ARE EXEMPTED BY TSCA FROM THE
PROVISIONS OF THE ACT. CERCLA: REPORTABLE QUANTITY OF EPA
HAZARDOUS SUBSTANCES IN THIS PRODUCT: ETHYLENE GL YCOL: RQ=5000 LB,
PRODUCT RQ=100,000 LB.