EEEPF - TETRAHYDRONAPHTHALENE
- MSDS: EEEPF
- Manufacturer: MATHESON TRI GAS INC
- Product Name: TETRAHYDRONAPHTHALENE
- National Stock Number: -
Product Identification
Product ID:TETRAHYDRONAPHTHALENE
MSDS Date:Jan 24 1989
MSDS Number: EEEPF
Kit Part:=== Responsible Party ===
Company Name:MATHESON TRI-GAS, INC.
Address:959 ROUTE 46 EAST
City:PARSIPPANY
State:NJ
ZIP:07054-0624
Country:US
Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)
780-471-4036
Chemtrec Ind/Phone:18004249300
Contractor
Telephone: (USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)
Ingredients
TETRAHYDRONAPHTHALENE
CAS: 119-64-2
Fraction By Weight: 100.0%
Hazards
Reports of Carcinogenicity:NTP:No IARC:No OSHA:No
Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE:
irritation, nausea, vomiting, headache, drowsiness, symptoms of
drunkenness, kidney damage, liver damage LONG TERM EXPOSURE: no
information on significant adverse effects SKIN CONTACT: SHORT TERM
EXPOSURE: same as effects reported in short term inhalation,
irritation, nausea, kidney damage, liver damage LONG TERM EXPOSURE:
same as effects reported in short term exposure EYE CONTACT: SHORT
TERM EXPOSURE: irritation, tearing LONG TERM EXPOSURE: same as
effects reported in short term exposure INGESTION: SHORT TERM
EXPOSURE: nausea, vomiting, symptoms of drunkenness, kidney damage,
liver damage LONG TERM EXPOSURE: same as effects reported in long
term inhalation
Medical Cond Aggravated by Exposure:
First Aid
First Aid: INHALATION: If adverse effects occur, remove to
uncontaminated area. Give artificial respiration if not breathing.
Get immediate medical attention. SKIN CONTACT: Wash skin with soap
and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention, if needed. Thoroughly
clean and dry contaminated clothing and shoes before reuse. EYE
CONTACT: Flush eyes with plenty of water for at least 15 minutes.
Then get immediate medical attention. INGESTION: Contact local
poison control center or physician immediately. Never make an
unconscious person vomit or drink fluids. If vomiting occurs, keep
head lower than hips to help prevent aspiration. If person is
unconscious, turn head to side. Get medical attention immediately.
Fire Fighting
Flash Point:160 F (71 C) (CC)
Autoignition Temp:725 F (385 C)
Lower Limits:0.8% @ 100 C
Upper Limits:5.0% @ 150 C
Extinguishing Media:regular dry chemical, carbon dioxide, water,
regular foam Large fires: Use regular foam or flood with fine water
spray.
Fire Fighting Procedures:Move container from fire area if it can be
done without risk. Cool containers with water spray until well
after the fire is out. Stay away from the ends of tanks. For fires
in cargo or storage area: Cool containers with water from unmanned
hose holder or monitor nozzles until well after fire is out. If
this is impossible then take the following precautions: Keep
unnecessary people away, isolate hazard area and deny entry. Let
the fire burn. Withdraw immediately in case of rising sound from
venting safety device or any discoloration of tanks due to fire.
For tank, rail car or tank truck: Evacuation radius: 800 meters
(1/2 mile). Do not attempt to extinguish fire unless flow of
material can be stopped first. Flood with fine water spray. Do not
scatter spilled material with high-pressure water streams. Cool
containers with water spray until well after the fire is out. Apply
water from a protected location or from a safe distance. Avoid
inhalation of material ocombustion by-products. Stay upwind and
keep out of low areas.
Unusual Fire/Explosion Hazard:Moderate fire hazard. Vapor/air mixtures
are explosive above flash point. The vapor is heavier than air.
Vapors or gases may ignite at distant ignition sources and flash
back.
Accidental Release
Spill Release Procedures:Avoid heat, flames, sparks and other sources
of ignition. Stop leak if possible without personal risk. Reduce
vapors with water spray. Small spills: Absorb with sand or other
non-combustible material. Collect spilled material in appropriate
container for disposal. Large spills: Dike for later disposal.
Remove sources of ignition. Keep unnecessary people away, isolate
hazard area and deny entry.
Neutralizing Agent:
Handling
Handling and Storage Precautions:Store and handle in accordance with
all current regulations and standards. Subject to storage
regulations: U.S. OSHA 29 CFR 1910.106. May form explosive
peroxides. Store in a tightly closed container. Avoid contact with
light. Store in a cool, dry place. Monitor inhibitor content. Do
not evaporate or distill to dryness. Keep separated from
incompatible substances.
Other Precautions:
Exposure Controls
Respiratory Protection:Under conditions of frequent use or heavy
exposure, respiratory protection may be needed. Respiratory
protection is ranked in order from minimum to maximum. Consider
warning properties before use. Any supplied-air respirator with a
full facepiece that is operated in a pressure-demand or other
positive-pressure mode. Any self-contained breathing apparatus that
has a full facepiece and is operated in a pressure-demand or other
positive-pressure mode. For Unknown Concentrations or Immediately
Dangerous to Life or Health - Any supplied-air respirator with full
facepiece and operated in a pressure-demand or other
positive-pressure mode in combination with a separate escape
supply. Any self-contained breathing apparatus with a full
facepiece.
Ventilation:Provide local exhaust or process enclosure ventilation
system. Ventilation equipment should be explosion-resistant if
explosive concentrations of material are present. Ensure compliance
with applicable exposure limits.
Protective Gloves:Wear appropriate chemical resistant gloves.
Eye Protection:Wear splash resistant safety goggles. Provide an
emergency eye wash fountain and quick drench shower in the
immediate work area.
Other Protective Equipment:Wear appropriate chemical resistant
clothing.
Supplemental Safety and Health
TETRAHYDRONAPHTHALENE: No occupational exposure limits established.
Chemical Properties
Boiling Pt:406 F (208 C)
Melt/Freeze Pt:-33 F (-36 C)
Vapor Pres:1.0 mmHg @ 38 C
Vapor Density:4.55
Spec Gravity:0.9702
pH:Not available
Evaporation Rate & Reference:Not available
Solubility in Water:insoluble
Appearance and Odor:PHYSICAL STATE:liquid COLOR:colorless ODOR:distinct
odor
Corrosion Rate:
Stability
Stability Indicator/Materials to Avoid:May form explosive peroxides.
Avoid prolonged storage or contact with air, light or storage and
use above room temperature. Explosive if dry.
Stability Condition to Avoid:Avoid heat, flames, sparks and other
sources of ignition. Containers may rupture or explode if exposed
to heat. Keep out of water supplies and sewers.
Hazardous Decomposition Products:Thermal decomposition products: oxides
of carbon Thermal decomposition products: oxides of carbon
Conditions to Avoid Polymerization:Will not polymerize.
Disposal
Waste Disposal Methods:Dispose in accordance with all applicable
regulations.
Toxicology
Toxicological Information:TETRAHYDRONAPHTHALENE: IRRITATION DATA: 500
mg open skin-rabbit severe TOXICITY DATA: 275 ppm inhalation-guinea
pig LC50; 17300 ul/kg skin-rabbit LD50; 1620 ul/kg oral-rat LD50
LOCAL EFFECTS: Irritant: inhalation, skin, eye ACUTE TOXICITY
LEVEL: Toxic: inhalation Moderately Toxic: ingestion Slightly
Toxic: dermal absorption TARGET ORGANS: central nervous system
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: respiratory disorders,
skin disorders and allergies ADDITIONAL DATA: Alcohol may enhance
the toxic effects.
Other Information
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ecology
Ecological:ECOTOXICITY DATA: INVERTEBRATE TOXICITY: 2412 ug/L 48
hour(s) EC50 (Immobilization) Water flea (Daphnia pulex)
Transport
Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME:
Toxic liquids, organic, n.o.s. (TETRAHYDRONAPHTHALENE) ID NUMBER:
UN2810 HAZARD CLASS OR DIVISION: 6.1 PACKING GROUP: II LABELING
REQUIREMENTS: Poison
Regulatory
SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY
HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE
III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not
regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS
CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: Yes
REACTIVE: No SUDDEN RELEASE: No SARA TITLE III SECTION 313 (40
CFR 372.65): Not regulated.
Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS
SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY
(29CFR1910.119): Not regulated.
State Regulatory Information: California Proposition 65: Not regulated.