EEERE - 1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE

  • MSDS: EEERE
  • Manufacturer: MATHESON TRI GAS INC
  • Product Name: 1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE
  • National Stock Number: -
Product Identification

Product ID:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE
MSDS Date:Jan 24 1989
MSDS Number: EEERE
Kit Part:=== Responsible Party ===
Company Name:MATHESON TRI-GAS, INC.
Address:959 ROUTE 46 EAST
City:PARSIPPANY
State:NJ
ZIP:07054-0624
Country:US
Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)
780-471-4036
Chemtrec Ind/Phone:18004249300

Contractor
MATHESON TRI-GAS, INC.
WHITBY, L1N 5R9 07054-0624 ONTARIO, CANADA

Telephone: (USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)

Ingredients

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE

CAS: 76-13-1

Fraction By Weight: 100.0%

Hazards

Reports of Carcinogenicity:NTP:No IARC:No OSHA:No
Medical Cond Aggravated by Exposure:

First Aid

First Aid: INHALATION: If adverse effects occur, remove to
uncontaminated area. Give artificial respiration if not breathing.
Get immediate medical attention. SKIN CONTACT: Wash skin with soap
and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention, if needed. Thoroughly
clean and dry contaminated clothing and shoes before reuse. EYE
CONTACT: Flush eyes with plenty of water for at least 15 minutes.
Then get immediate medical attention. INGESTION: If a large amount
is swallowed, get medical attention.

Fire Fighting

Flash Point:No data available.
Autoignition Temp:1256 F (680 C)
Extinguishing Media:regular dry chemical, carbon dioxide, water,
regular foam Large fires: Use regular foam or flood with fine water
spray.
Fire Fighting Procedures:Move container from fire area if it can be
done without risk. Do not scatter spilled material with
high-pressure water streams. Dike for later disposal. Use
extinguishing agents appropriate for surrounding fire. Avoid
inhalation of material or combustion by-products. Stay upwind and
keep out of low areas.
Unusual Fire/Explosion Hazard:Slight fire hazard.

Accidental Release

Spill Release Procedures:Stop leak if possible without personal risk.
Small spills: Absorb with sand or other non-combustible material.
Collect spilled material in appropriate container for disposal.
Keep unnecessary people away, isolate hazard area and deny entry.
Neutralizing Agent:

Handling

Handling and Storage Precautions:Store and handle in accordance with
all current regulations and standards. Keep separated from
incompatible substances. Store in a tightly closed container. Store
in a cool, dry place. Store in a well-ventilated area.
Other Precautions:

Exposure Controls

Respiratory Protection:The following respirators and maximum use
concentrations are drawn from NIOSH and/or OSHA. 2000 ppm Any
supplied-air respirator. Any self-contained breathing apparatus
with a full facepiece. Escape - Any air-purifying respirator with a
full facepiece and an organic vapor canister. Any appropriate
escape-type, self-contained breathing apparatus. For Unknown
Concentrations or Immediately Dangerous to Life or Health - Any
supplied-air respirator with full facepiece and operated in a
pressure-demand or other positive-pressure mode in combination with
a separate escape supply. Any self-contained breathing apparatus
with a full facepiece.
Ventilation:Based on available information, additional ventilation is
not required. Ensure compliance with applicable exposure limits.
Protective Gloves:Wear appropriate chemical resistant gloves.
Eye Protection:Wear splash resistant safety goggles. Provide an
emergency eye wash fountain and quick drench shower in the
immediate work area.
Other Protective Equipment:Wear appropriate chemical resistant
clothing.
Supplemental Safety and Health
1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE:
1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON TF): 1000 ppm (7600
mg/m3) OSHA TWA 1250 ppm (9590 mg/m3) OSHA STEL (vacated by 58 FR
35338, June 30, 1993) 1000 ppm ACGIH TWA 1250 ppm ACGIH STEL 1000
ppm (7600 mg/m3) NIOSH recommended TWA 10 hour(s) 1250 ppm (9500
mg/m3) NIOSH recommended STEL

Chemical Properties

Boiling Pt:118 F (48 C)
Melt/Freeze Pt:-33 F (-36 C)
Vapor Pres:284 mmHg @ 20 C
Vapor Density:6.47
Spec Gravity:1.5635 @ 25 C
pH:Not available
Evaporation Rate & Reference:0.45 (acetone=1)
Solubility in Water:0.017% @ 25 C
Appearance and Odor:PHYSICAL STATE:liquid APPEARANCE:clear
COLOR:colorless PHYSICAL FORM:volatile liquid ODOR:sweet odor
Corrosion Rate:

Stability

Stability Indicator/Materials to Avoid:Stable at normal temperatures
and pressure.
Stability Condition to Avoid:Avoid heat, flames, sparks and other
sources of ignition. Avoid contact with incompatible materials.
Hazardous Decomposition Products:Thermal decomposition products:
halogenated compounds, oxides of carbon Thermal decomposition
products: halogenated compounds, oxides of carbon
Conditions to Avoid Polymerization:Will not polymerize.

Disposal

Waste Disposal Methods:Dispose in accordance with all applicable
regulations.

Toxicology

Toxicological Information:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE:
IRRITATION DATA: 500 mg open skin-rabbit mild; 500 mg/24 hour(s)
skin-rabbit mild TOXICITY DATA: 38500 ppm/4 hour(s) inhalation-rat
LC50; 43 gm/kg oral-rat LD50 CARCINOGEN STATUS: ACGIH: A4 -Not
Classifiable as a Human Carcinogen ACUTE TOXICITY LEVEL: Slightly
Toxic: inhalation Relatively Non-toxic: ingestion TARGET ORGANS:
central nervous system MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
heart or cardiovascular disorders, heart problems, respiratory
disorders, skin disorders and allergies REPRODUCTIVE EFFECTS DATA:
Available. ADDITIONAL DATA: Stimulants such as epinephrine may
induce ventricular fibrillation.

Other Information

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecology

Ecological:Not available

Transport

Transport Information:U.S. DEPARTMENT OF TRANSPORTATION: No
classification assigned.

Regulatory

SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY
HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE
III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not
regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS
CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: No
REACTIVE: No SUDDEN RELEASE: No SARA TITLE III SECTION 313 (40
CFR 372.65): 1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON TF)
Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS
SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY
(29CFR1910.119): Not regulated.
State Regulatory Information: California Proposition 65: Not regulated.