EEESU - CHLOROFORM

Product Identification

Product ID:CHLOROFORM
MSDS Date:Jan 24 1989
MSDS Number: EEESU
Kit Part:=== Responsible Party ===
Company Name:MATHESON TRI-GAS, INC.
Address:959 ROUTE 46 EAST
City:PARSIPPANY
State:NJ
ZIP:07054-0624
Country:US
Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)
780-471-4036
Chemtrec Ind/Phone:18004249300

Contractor
MATHESON TRI-GAS, INC.
WHITBY, L1N 5R9 07054-0624 ONTARIO, CANADA

Telephone: (USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)

Ingredients

CHLOROFORM

CAS: 67-66-3

Fraction By Weight: >99%


STABILIZERS

Fraction By Weight: <0.1%

Hazards

Reports of Carcinogenicity:NTP:Yes IARC:Yes OSHA:No
Medical Cond Aggravated by Exposure:

First Aid

First Aid: INHALATION: If adverse effects occur, remove to
uncontaminated area. Give artificial respiration if not breathing.
Get immediate medical attention. SKIN CONTACT: Wash skin with soap
and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention, if needed. Thoroughly
clean and dry contaminated clothing and shoes before reuse. EYE
CONTACT: Flush eyes with plenty of water for at least 15 minutes.
Then get immediate medical attention. INGESTION: For ingestion,
consider gastric lavage. Consider oxygen. Avoid epinephrine. Get
medical attention immediately.

Fire Fighting

Flash Point:No data available.
Extinguishing Media:regular dry chemical, regular foam, water Large
fires: Use regular foam or flood with fine water spray.
Fire Fighting Procedures:Move container from fire area if it can be
done without risk. Fight large fires from a protected location or
safe distance. Stay away from the ends of tanks. Dike for later
disposal. Do not scatter spilled material with high-pressure water
streams.
Unusual Fire/Explosion Hazard:Negligible fire hazard.

Accidental Release

Neutralizing Agent:

Handling

Handling and Storage Precautions:Store and handle in accordance with
all current regulations and standards. Notify State Emergency
Response Commission for storage or use at amounts greater than or
equal to the TPQ (U.S. EPA SARA Section 302). SARA Section 303
requires facilities storing a material with a TPQ to participate in
local emergency response planning (U.S. EPA 40 CFR 355.30). Store
in a cool, dry place. Store in a well-ventilated area. Keep
separated from incompatible substances. Keep separated from
incompatible substances.
Other Precautions:

Exposure Controls

Respiratory Protection:The following respirators and maximum use
concentrations are drawn from NIOSH and/or OSHA. At any detectable
concentration - Any self-contained breathing apparatus that has a
full facepiece and is operated in a pressure-demand or other
positive-pressure mode. Any supplied-air respirator with full
facepiece and operated in a pressure-demand or other
positive-pressure mode in combination with a separate escape
supply. Escape - Any air-purifying respirator with a full facepiece
and an organic vapor canister. Any appropriate escape-type,
self-contained breathing apparatus. For Unknown Concentrations or
Immediately Dangerous to Life or Health - Any supplied-air
respirator with full facepiece and operated in a pressure-demand or
other positive-pressure mode in combination with a separate escape
supply. Any self-contained breathing apparatus with a full
facepiece.
Ventilation:Provide local exhaust or process enclosure ventilation
system. Ensure compliance with applicable exposure limits.
Protective Gloves:Wear appropriate chemical resistant gloves.
Eye Protection:Wear splash resistant safety goggles. Provide an
emergency eye wash fountain and quick drench shower in the
immediate work area.
Other Protective Equipment:Wear appropriate chemical resistant
clothing.
Supplemental Safety and Health
CHLOROFORM: 50 ppm (240 mg/m3) OSHA ceiling 2 ppm (9.78 mg/m3) OSHA
TWA (vacated by 58 FR 35338, June 30, 1993) 10 ppm ACGIH TWA 2 ppm
(9.78 mg/m3) NIOSH recommended STEL 60 minute(s)

Chemical Properties

Boiling Pt:144 F (62 C)
Melt/Freeze Pt:-83 F (-64 C)
Vapor Pres:160 mmHg @ 20 C
Vapor Density:4.12
Spec Gravity:1.4832
pH:Not available
Evaporation Rate & Reference:11.6 (butyl acetate=1)
Solubility in Water:0.82% @ 20 C
Appearance and Odor:PHYSICAL STATE:liquid APPEARANCE:clear
COLOR:colorless PHYSICAL FORM:volatile liquid ODOR:sweet odor and
taste
Corrosion Rate:

Stability

Stability Indicator/Materials to Avoid:Stable at normal temperatures
and pressure.
Stability Condition to Avoid:Avoid heat, flames, sparks and other
sources of ignition. Containers may rupture or explode if exposed
to heat.
Hazardous Decomposition Products:Thermal decomposition products: oxides
of chlorine, carbon, phosgene, chlorine, acid halides Thermal
decomposition products: oxides of chlorine, carbon, phosgene,
chlorine, acid halides
Conditions to Avoid Polymerization:Will not polymerize.

Disposal

Waste Disposal Methods:Dispose in accordance with all applicable
regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262.
Hazardous Waste Number(s): U044. Hazardous Waste Number(s): D022.
Dispose of in accordance with U.S. EPA 40 CFR 262 for
concentrations at or above the Regulatory level. Regulatory level-
6.0 mg/L.

Toxicology

Toxicological Information:CHLOROFORM: IRRITATION DATA: 10 mg/24 hour(s)
open skin-rabbit mild; 500 mg/24 hour(s) skin-rabbit mild; 148 mg
eyes-rabbit; 20 mg/24 hour(s) eyes-rabbit moderate TOXICITY DATA:
47702 mg/m3/4 hour(s) inhalation-rat LC50; >20 gm/kg skin-rabbit
LD50; 695 mg/kg oral-rat LD50 CARCINOGEN STATUS: NTP: Anticipated
Human Carcinogen; IARC: Human Inadequate Evidence, Animal
Sufficient Evidence, Group 2B; ACGIH: A3 -Animal Carcinogen LOCAL
EFFECTS: Irritant: inhalation, skin, eye ACUTE TOXICITY LEVEL:
Moderately Toxic: ingestion Slightly Toxic: inhalation TARGET
ORGANS: central nervous system, liver, kidneys MEDICAL CONDITIONS
AGGRAVATED BY EXPOSURE: history of alcoholism, eye disorders, heart
problems, kidney disorders, liver disorders, respiratory disorders,
skin disorders and allergies TUMORIGENIC DATA: Available. MUTAGENIC
DATA: Available. REPRODUCTIVE EFFECTS DATA: Available. ADDITIONAL
DATA: May be excreted in breast milk. Alcohol may enhance the toxic
effects. Stimulants such as epinephrine may induce ventricular
fibrillation.

Other Information

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecology

Ecological:ECOTOXICITY DATA: FISH TOXICITY: 66800 ug/L 96 hour(s) LC50
(Mortality) Rainbow trout,donaldson trout (Oncorhynchus mykiss)
INVERTEBRATE TOXICITY: 32000 ug/L 96 hour(s) NOEC (Mortality) Pink
shrimp (america) (Penaeus duorarum) ALGAL TOXICITY: >3200000 ug/L
48 hour(s) (Population Growth) Cryptomonad (Chilomonas paramecium)
OTHER TOXICITY: 270 ug/L 7 hour(s) EC50 (Teratogenesis) Spring
peeper (Hyla crucifer) FATE AND TRANSPORT: BIOCONCENTRATION: 690
Ci/mol 6 hour(s) BCF (Residue) Green algae (Selenastrum
capricornutum) 13.9 Ci/mol

Transport

Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME:
Chloroform ID NUMBER: UN1888 HAZARD CLASS OR DIVISION: 6.1 PACKING
GROUP: III LABELING REQUIREMENTS: Poison

Regulatory

SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY
HAZARDOUS SUBSTANCES (40 CFR 355.30): Chloroform: 10000LBSTPQ
SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR
355.40): Chloroform: 10LBSRQ SARA TITLE III SARA SECTIONS
311/312 HAZARDOUS CATEGORIES (40 CFR 370.21): ACUTE: Yes
CHRONIC: Yes FIRE: No REACTIVE: No SUDDEN RELEASE: No SARA
TITLE III SECTION 313 (40 CFR 372.65): Chloroform
Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS
SUBSTANCES (40 CFR 302.4): Chloroform: 10LBSRQ OSHA PROCESS SAFETY
(29CFR1910.119): Not regulated.
State Regulatory Information: California Proposition 65: Known to the
state of California to cause the following: Chloroform Cancer (Oct
01, 1987)